Abstract:
The Schmidt rearrangement of methyl furoxanyl ketones and furoxancarboxylic acids has been carried out for the first time, exemplified by 3,4-diacetylfuroxan and 4-carboxy-3-(ethoxycarbonyl)furoxan, and this reaction has been shown to be a convenient method for the preparation of aminofuroxans.
Document Type:
Article
Language: English
Citation:
N. N. Makhova, A. N. Blinnikov, L. I. Khmel'nitskii, “The Schmidt Rearrangement of Methyl Furoxanyl Ketones and Furoxancarboxylic Acids: a New Synthetic Route to Aminofuroxans”, Mendeleev Commun., 5:2 (1995), 56–58
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https://www.mathnet.ru/eng/mendc5029
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