Abstract:
Homolytic cycloaddition of butane-1,4-dithiol with alkynes offers a facile one-pot route to 8-membered 1,4-dithiocanes and 16-and 24-membered crown thioethers, 1,4,9,12-tetrathiacyclohexadecanes and 1,4,9,12,17,20-hexathiacyclotetracosanes.
Document Type:
Article
Language: English
Citation:
E. I. Troyanskii, R. F. Ismagilov, E. N. Korneeva, M. S. Pogosyan, G. I. Nikishin, “An Approach to 8-, 16- and 24-Membered Sulfur-containing Heterocycles via Homolytic Cycloaddition of Alkynes with Butane-1,4-dithiol”, Mendeleev Commun., 5:1 (1995), 18–20
Linking options:
https://www.mathnet.ru/eng/mendc5015
https://www.mathnet.ru/eng/mendc/v5/i1/p18
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V. V. Litvinova, A. V. Anisimov, “Thiacrown compounds: Synthesis and properties. (Review)”, Chem Heterocycl Compd, 35:12 (1999), 1385
E. I. Troyansky, D. V. Demchuk, G. I. Nikishin, “Homolytic addition of dithiols to alkynes: A new approach to the construction of dithiacyclanes and crown thioethers”, Russ Chem Bull, 46:7 (1997), 1199
E. I. Troyanskii, M. S. Pogosyan, N. M. Samoshina, G. I. Nikishin, V. V. Samoshin, L. K. Shpigun, N. E. Kopytova, P. M. Kamilova, “Crown thioethers and 1,4-dithiacyclanes immobilized on silica carrier: preparation and studies of complexation affinity towards metal ions”, Mendeleev Commun., 6:1 (1996), 9–11
Emmanuil I. Troyansky, Rustem F. Ismagilov, Yury A. Strelenko, Vyacheslav V. Samoshin, Dmitry V. Demchuk, Gennady I. Nikishin, Sergey V. Lindeman, Viktor V. Khrustalyov, Yury T. Struchkov, “Remote asymmetric induction in free radical cycloaddition leading to trans-cyclohexano-fused 12-membered crown thioethers”, Tetrahedron Letters, 36:13 (1995), 2293
Emmanuil I. Troyansky, Rustem F. Ismagilov, Vyacheslav V. Samoshin, Yury A. Strelenko, Dmitry V. Demchuk, Gennady I. Nikishin, Sergey V. Lindeman, Viktor N. Khrustalyov, Yury T. Struchkov, “Stereoselective free radical cycloaddition-macrocyclization in facile synthesis of trans-cyclohexano-fused 12-membered crown thioethers”, Tetrahedron, 51:42 (1995), 11431
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