This article is cited in 5 scientific papers (total in 5 papers)
The unusual reaction of [8-(dimethylamino)methyl-1-naphthyl]phenylchlorosilane with fluoren-9-yllithium. Synthesis of kinetically stable dibenzosilafulvene
Abstract:
The first stable dibenzosilafulvene, 14-[8’-(dimethylamino)metliyl-l’-naplitliyl]-14-plienyl-14-silafluorenylide 1, was obtained in one step from fluoren-9-yllithium and [8-(dimethylamino)methyl-l-naphthyl]phenylchlorosilane 2 as a stable solvate with THF; the zwitterionic structure of 1 is established by 1H, 13C and 29Si NMR in solution and solid state and its reactions with crotonaldehyde, ethanol and triethylethylidene-λ5-phosphane are described.
Document Type:
Article
Language: English
Citation:
I. V. Borisova, N. N. Zemlyansky, A. K. Shestakova, Yu. A. Ustynyuk, “The unusual reaction of [8-(dimethylamino)methyl-1-naphthyl]phenylchlorosilane with fluoren-9-yllithium. Synthesis of kinetically stable dibenzosilafulvene”, Mendeleev Commun., 6:6 (1996), 229–230
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https://www.mathnet.ru/eng/mendc4990
https://www.mathnet.ru/eng/mendc/v6/i6/p229
This publication is cited in the following 5 articles:
P.D. Lickiss, Comprehensive Heterocyclic Chemistry III, 2008, 913
NIKOLAI N. ZEMLYANSKY, IRINA V. BORISOVA, YURI A. USTYNYUK, Advances in Organometallic Chemistry, 49, 2003, 35
M. S. Nechaev, I. V. Borisova, N. N. Zemlyanskii, D. N. Laikov, Yu. A. Ustynyuk, “Heteroorganic betaines”, Russ Chem Bull, 49:11 (2000), 1823
N. N. Zemlyanskii, I. V. Borisova, A. K. Shestakova, Yu. A. Ustynyuk, E. A. Chernyshev, “Synthesis of the first kinetically stable dibenzosilafulvene”, Russ Chem Bull, 47:3 (1998), 469
I. V. BORISOVA, N. N. ZEMLYANSKII, A. K. SHESTAKOVA, Y. A. USTYNYUK, “ChemInform Abstract: Unusual Reaction of (8‐(Dimethylamino)methyl‐1‐naphthyl) phenylchlorosilane with Fluoren‐9‐yllithium. Synthesis of Kinetically Stable Dibenzosilafulvene.”, ChemInform, 28:15 (1997)
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