Abstract:
The use of substrate probes for establishing the nature of intermediates and the mechanism of alkane oxidation by peroxides upon catalysis by binuclear iron complexes {[Fe2OL2 (H2O)2](ClO4)4, where L = bpy, 4,4′-Me2bpy or 5-NO2phen (bpy = bipyridine, phen = phenanthroline)}, the analysis of the dependence of test parameters on the nature of a substituent in a ligand and the effect of dioxygen all make it possible to diagnose a two-electron mechanism for the transfer of the oxygen atom from peroxide to the C–H bond of an alkane via metal complexes.
Document Type:
Article
Language: English
Citation:
V. S. Kulikova, O. N. Gritsenko, A. A. Shteinman, “Molecular mechanism of alkane oxidation involving binuclear iron complexes”, Mendeleev Commun., 6:3 (1996), 119–120
Linking options:
https://www.mathnet.ru/eng/mendc4942
https://www.mathnet.ru/eng/mendc/v6/i3/p119
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