K. A. Udachin, J. Lipkowski, “Channel polyhydrate (C2H5)4NF.11H2O”, Mendeleev Commun., 6:3 (1996), 92

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Mendeleev Communications, 1996, Volume 6, Issue 3, Pages 92–93
DOI: https://doi.org/10.1070/MC1996v006n03ABEH000593 (Mi mendc4927)

This article is cited in 9 scientific papers (total in 9 papers)

Channel polyhydrate (C₂H₅)₄NF.11H₂O

K. A. Udachin^a, J. Lipkowski^b

^a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland

Full-text PDF (474 kB) Citations (9)

DOI: https://doi.org/10.1070/MC1996v006n03ABEH000593

Abstract: The phase diagram of the system (C₂H₅)₄NF–H₂O, has been studied. The polyhydrates (C₂H₅)₄NF·5H₂O and (C₂H₅)₄NF·11H₂O, which melt congruently at 24.8 and – 13.6 °C respectively, have been found in this system. The hydrate (C₂H₅)₄NF-11H₂O has a channel–cavity structure. Water and fluoride anions form a three-dimensional framework consisting of channels and cavities. The channels are filled with cations (C₂H₅)₄N⁺, and the cavities are vacant. The polyhydrate (C₂H₅)₄NF·11H₂O has the following crystallographic parameters: a = 12.393(3), b = 22.595(7) c = 11.483(3) A (T = –100°C), space group Pnnm, Z = 6.

Document Type: Article

Language: English

Citation: K. A. Udachin, J. Lipkowski, “Channel polyhydrate (C₂H₅)₄NF.11H₂O”, Mendeleev Commun., 6:3 (1996), 92–93

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https://www.mathnet.ru/eng/mendc4927

https://www.mathnet.ru/eng/mendc/v6/i3/p92

This publication is cited in the following 9 articles:

A.Y. Manakov, V.I. Kosyakov, S.F. Solodovnikov, Comprehensive Supramolecular Chemistry II, 2017, 161
L. S. Aladko, “Hydrate formation in the system tetraethylammonium bromide-water”, Russ J Gen Chem, 82:12 (2012), 1913
L. S. Aladko, “Hydrate formation in the system tetraethylammonim chloride-water”, Russ J Gen Chem, 79:8 (2009), 1613
L. S. Aladko, A. Yu. Manakov, A. G. Ogienko, A. I. Ancharov, “New data on phase diagram and clathrate formation in the system water–isopropyl alcohol”, J Incl Phenom Macrocycl Chem, 63:1-2 (2009), 151
K. A. Udachin, J. Lipkowski, “Water-fluorine chains in (18-crown-6)·NH4F·3H2O hydrate”, J Struct Chem, 46:S1 (2005), S84
Michael Wiebcke, Jürgen Felsche, “The tetraethylammonium cation in a double three-ring silicate heteronetwork clathrate and a polyhedral clathrate hydrate: low-temperature single-crystal X-ray diffraction studies on (NEt4)6[Si6O15]·40.8H2O and NEt4OH·9H2O”, Microporous and Mesoporous Materials, 43:3 (2001), 289
Janusz Lipkowski, Konstantin Udachin, Yurij Simonov, Dymitry Soldatov, Current Challenges on Large Supramolecular Assemblies, 1999, 157
K. A. Udachin, J. Lipkowski, “Layered polyhydrate 18-crown-6C3H7NH3F.10H2O”, Mendeleev Commun., 6:5 (1996), 195–197
K. A. Udachin, J. Lipkowski, “Layered polyhydrate 18-crown-6·12H2O”, Mendeleev Commun., 6:4 (1996), 133–134

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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