This article is cited in 4 scientific papers (total in 4 papers)
Mild alkane functionalisation leading to ethers: oxidative alkoxylation of cyclohexane with the dibromobis(phosphine)palladium(II)–sodium alkoxide system
Abstract:
Dibromobis(phosphine)palladium(II) complexes, PdBr2(L)2 [L = PPh3, P(p-Tol)3], react with cyclohexane and an alcoholic solution of sodium alkoxide, NaOR (R = Me, Et, Pri), at 30–60°C affording the corresponding alkyl cyclohex-1-enyl ethers, ROC6H9, in 30–140% yield on palladium both under argon and under air; benzene is inert under the reaction conditions, sodium tert-butoxide does not enter the hydrocarbon alkoxylation.
Document Type:
Article
Language: English
Citation:
A. N. Vedernikov, M. D. Sayakhov, B. N. Solomonov, “Mild alkane functionalisation leading to ethers: oxidative alkoxylation of cyclohexane with the dibromobis(phosphine)palladium(II)–sodium alkoxide system”, Mendeleev Commun., 7:5 (1997), 205–206
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https://www.mathnet.ru/eng/mendc/v7/i5/p205
This publication is cited in the following 4 articles:
Petr Sehnal, Richard J. K. Taylor, Ian J. S. Fairlamb, “Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis”, Chem. Rev., 110:2 (2010), 824
Catalysis by Metal Complexes, 21, Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, 2002, 127
Abdelkhalek Riahi, Jacques Muzart, “Unexpected regioselective formation of internal η3-allylpalladium chloride complexes from terminal alkenes and palladium chloride in 1,2-dichloroethane”, Journal of Organometallic Chemistry, 585:2 (1999), 256
A. N. VEDERNIKOV, M. D. SAYAKHOV, B. N. SOLOMONOV, “ChemInform Abstract: Mild Alkane Functionalization Leading to Ethers: Oxidative Alkoxylation of Cyclohexane with the Dibromobis(phosphine)palladium(II)—Sodium Alkoxide System.”, ChemInform, 29:9 (1998)
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