Abstract:
The synthesis of a series of cyclic organoaluminium compounds, aluminacyclopropanes, which have never previously been described, has been carried out by α-olefin cyclometallation with EtAlCl2 in the presence of a chlorine ion acceptor, metallic magnesium and Cp2TiCl2 (Cp = η5-C5H5) catalyst.
Document Type:
Article
Language: English
Citation:
U. M. Dzhemilev, A. G. Ibragimov, L. O. Khafizova, S. V. Rusakov, L. M. Khalilov, “The first example of synthesis of aluminacyclopropanes catalysed by (η5-C5H5)2TiCl2”, Mendeleev Commun., 7:5 (1997), 198–199
Linking options:
https://www.mathnet.ru/eng/mendc4854
https://www.mathnet.ru/eng/mendc/v7/i5/p198
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