Abstract:
The 1-(2-aminoethyl)aziridine (aziridine dimer) 1 reacts with acetylene dicarboxylates to give 1,4-diaza- 5-oxobicyclo[4.3.0]nonanes (7-azaindolizines) 3 together with the usual enamine adducts 4; the product structures are confirmed spectroscopically and, in the 3 also by X-ray diffraction and by an independent synthesis from furan 5.
Document Type:
Article
Language: English
Citation:
R. G. Kostyanovsky, Yu. I. El'natanov, I. I. Chervin, M. Yu. Antipin, A. V. Ivanov, “Unusual reaction of aziridine dimer with acetylene dicarboxylates”, Mendeleev Commun., 7:2 (1997), 56–58
Linking options:
https://www.mathnet.ru/eng/mendc4780
https://www.mathnet.ru/eng/mendc/v7/i2/p56
This publication is cited in the following 2 articles:
Pieterjan Winant, Tomas Horsten, Shaiani Gil de Melo, Flavio Emery, Wim Dehaen, “A Review of the Synthetic Strategies toward Dihydropyrrolo[1,2-a]Pyrazinones”, Organics, 2:2 (2021), 118
R. G. KOSTYANOVSKY, YU. I. EL'NATANOV, I. I. CHERVIN, M. YU. ANTIPIN, K. A. LYSSENKO, “ChemInform Abstract: Unusual Reaction of Aziridine Dimer with Acetylene Dicarboxylates”, ChemInform, 28:37 (1997)
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