Abstract:
Previously unknown tris(nitroxymethyl)methylamine has been synthesised as the free base by nitration of tris(hydroxymethyl)- methylamine with nitryl fluoride; by oxidation of tris(nitroxymethyl)methylamine with sodium nitrite in aqueous nitric acid, tris(nitroxymethyl)nitrosomethane, the first representative of aliphatic nitrates containing a nitroso-group, is prepared for the first time.
Document Type:
Article
Language: English
Citation:
B. S. Fedorov, M. A. Fadeev, L. T. Eremenko, “Tris(nitroxymethyl)methylamine and tris(nitroxymethyl)nitrosomethane”, Mendeleev Commun., 7:1 (1997), 40–41
Linking options:
https://www.mathnet.ru/eng/mendc4773
https://www.mathnet.ru/eng/mendc/v7/i1/p40
This publication is cited in the following 3 articles:
Sergey A. Rzhevskiy, Lidiya I. Minaeva, Maxim A. Topchiy, Igor N. Melnikov, Vitaly G. Kiselev, Alla N. Pivkina, Igor V. Fomenkov, Andrey F. Asachenko, “Synthesis, Characterization, and Properties of High-Energy Fillers Derived from Nitroisobutylglycerol”, IJMS, 24:10 (2023), 8541
Tobias S. Hermann, Thomas M. Klapötke, Burkhard Krumm, Jörg Stierstorfer, “The Reagent‐depending Nitration of 1,3‐Dihydroxyacetone Dimer”, Zeitschrift anorg allge chemie, 643:2 (2017), 149
Brian G. Gowenlock, George B. Richter-Addo, “Preparations ofC-Nitroso Compounds”, Chem. Rev., 104:7 (2004), 3315
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