Abstract:
5,(n + 6)-Dimethoxy-1-oxabicyclo[n.4.0]alkanes undergo a previously unknown oxidative rearrangement into ω-(2-methoxytetrahydrofur- 2-yl)alkanoic esters during electrolysis in methanol.
Document Type:
Article
Language: English
Citation:
Yu. N. Ogibin, A. O. Terent'ev, A. I. Ilovaisky, G. I. Nikishin, “Electrooxidative rearrangement of 5,(n + 6)-dimethoxy-1-oxabicyclo[n.4.0]alkanes (n = 4, 10) into ω-(2-methoxytetrahydrofur-2-yl)alkanoic esters”, Mendeleev Commun., 8:6 (1998), 239–240
Linking options:
https://www.mathnet.ru/eng/mendc4747
https://www.mathnet.ru/eng/mendc/v8/i6/p239
This publication is cited in the following 4 articles:
Yuri N Ogibin, Alexandre O Terent'ev, Alexandre V Kutkin, Gennady I Nikishin, “A rearrangement of 1-hydroperoxy-2-oxabicycloalkanes into lactones of ω-acyloxy-(ω-3)-hydroxyalkanoic acids related to the Criegee reaction”, Tetrahedron Letters, 43:7 (2002), 1321
Michael Schmittel, Karl Peters, Eva-Maria Peters, Andreas Haeuseler, Holger Trenkle, “Radical Cation Ester Cleavage in Solution. Mechanism of the Mesolytic O-CO Bond Scission”, J. Org. Chem., 66:10 (2001), 3265
Yuri N. Ogibin, Alexander O. Terent'ev, Alexey I. Ilovaisky, Gennady I. Nikishin, “ChemInform Abstract: Electrooxidative Rearrangement of 5,(n + 6)‐Dimethoxy‐1‐oxabicyclo[n.4.0]alkanes (n = 4,10) into ω‐(2‐Methoxytetrahydrofur‐2‐yl)alkanoic Esters.”, ChemInform, 30:19 (1999)
Yu. N. Ogibin, A. O. Terent'ev, A. I. Ilovaisky, G. I. Nikishin, “Electroinduced oxidative transformation of 2,5-dioxabicyclo[4.4.0]decanes into 5-(1,3-dioxolan-2-yl)- and 5-(dimethoxymethyl)pentanoates”, Mendeleev Commun., 9:5 (1999), 194–196
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