Abstract:
On the basis of numerical simulation of the branching chain process of the decomposition of nitrogen trichloride it has been shown that suitable conditions for providing oscillating regimes are the following: (a) inclusion of adsorption–desorption of NCl3 on the reactor walls; (b) inclusion of nonlinear chain branching and breaking reactions.
Document Type:
Article
Language: English
Citation:
N. M. Rubtsov, “Kinetic mechanism and chemical oscillations in the branching chain decomposition of nitrogen trichloride”, Mendeleev Commun., 8:5 (1998), 173–176
Linking options:
https://www.mathnet.ru/eng/mendc4713
https://www.mathnet.ru/eng/mendc/v8/i5/p173
This publication is cited in the following 10 articles:
Men Xia, Yifan Jiang, Jianing Dai, Yongchun Liu, Chao Yan, Markku Kulmala, Tao Wang, “Chlorine Activation in Marine Air: Insights From Chemical Budgets of Molecular Chlorine and Hypochlorous Acid”, JGR Atmospheres, 130:6 (2025)
Nikolai M. Rubtsov, Springer Aerospace Technology, Key Factors of Combustion, 2017, 57
Nikolai M. Rubtsov, Springer Aerospace Technology, Key Factors of Combustion, 2017, 1
K. Maka, Graeme W. Norval, “Optimising chlorine compression design with vapour phase nitrogen trichloride destruction”, Can J Chem Eng, 91:4 (2013), 718
F. Gérardin, A. Cloteaux, M. Guillemot, M. Faure, J. C. André, “Photocatalytic Conversion of Gaseous Nitrogen Trichloride into Available Chlorine—Experimental and Modeling Study”, Environ. Sci. Technol., 47:9 (2013), 4628
J.I.H. Tavares Neto, K.D. Brito, L.G.S. Vasconcelos, J.J.N. Alves, M.F. Fossy, R.P. Brito, “Industrial and simulation analysis of the nitrogen trichloride decomposition process in electrolytic chlorine production”, Journal of Hazardous Materials, 142:1-2 (2007), 500
R. D. Coombe, J. V. Gilbert, S. S. Beaton, N. Mateljevic, “Photodissociation of Gaseous NCl3 at 193 and 249 nm”, J. Phys. Chem. A, 106:36 (2002), 8422
N. M. Rubtsov, V. D. Kotelkin, “Transition from isothermal to chain-thermal flame-propagation regimes in the branching-chain decomposition of nitrogen trichloride”, Mendeleev Commun., 12:1 (2002), 33–36
N. M. Rubtsov, V. D. Kotelkin, “Inhibition and promotion of an isothermal flame in the low-pressure thermal decomposition of nitrogen trichloride”, Mendeleev Commun., 12:6 (2002), 241–244
N. M. Rubtsov, V. D. Kotelkin, “On the nature of the upper limit of isothermal flame propagation in the branching-chain decomposition of nitrogen trichloride”, Mendeleev Commun., 11:2 (2001), 61–64
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