Abstract:
Decomposition of dimethyldioxirane in the presence of tris(bipyridine)ruthenium(II) complex (RuII) is accompanied by chemiluminescence (CL) in the infrared spectrum region (1270 nm) due to the formation of singlet oxygen; reaction between RuIII and superoxide ion, which is formed in this process via a sequence of electron-transfer reactions, is assumed to be a CL step.
Document Type:
Article
Language: English
Citation:
D. V. Kazakov, A. I. Voloshin, V. V. Shereshovets, V. N. Yakovlev, V. P. Kazakov, “Formation of singlet oxygen in the system tris(bipyridine)ruthenium(II)–dimethyldioxirane”, Mendeleev Commun., 8:5 (1998), 169–170
Linking options:
https://www.mathnet.ru/eng/mendc4711
https://www.mathnet.ru/eng/mendc/v8/i5/p169
This publication is cited in the following 1 articles:
Waldemar Adam, Dmitri V. Kazakov, Valeri P. Kazakov, “Singlet-Oxygen Chemiluminescence in Peroxide Reactions”, Chem. Rev., 105:9 (2005), 3371
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