Abstract:
The reaction of 2-amino-6-hydroxy-5,5-pentamethylene-1,1,1-trifluoro-2-hexen-4-one with ethylenediamine, in contrast to the similar reaction involving 2-amino-6-hydroxy-5,5-dimethyl-1,1,1-trifluoro-2-hexen-4-one, leads to 2-(3-hydroxymethyl-3,3-pentamethyleneacetonyl)-2-trifluoromethylimidazolidine.
Document Type:
Article
Language: English
Citation:
V. Ya. Sosnovskikh, M. Yu. Mel'nikov, “Unexpected synthesis of 2-(3-hydroxymethyl-3,3-pentamethyleneacetonyl)-2-trifluoromethylimidazolidine”, Mendeleev Commun., 8:1 (1998), 19–20
Linking options:
https://www.mathnet.ru/eng/mendc4635
https://www.mathnet.ru/eng/mendc/v8/i1/p19
This publication is cited in the following 4 articles:
V. Ya. Sosnovskikh, M. Yu. Mel'nikov, I. I. Vorontsov, “Reactions of aliphatic β-amino-β-(trichloromethyl)vinyl ketones with ethylenediamine. Synthesis and structures of 2-acetonylideneimidazolidines”, Russ Chem Bull, 49:7 (2000), 1245
V. Ya. Sosnovskikh, V. A. Kutsenko, “Reactions of aromatic and heteroaromatic β-amino-β-polyfluoroalkylvinyl ketones with ethylenediamine. A new synthesis ofN,N′-unsubstituted imidazolidines”, Russ Chem Bull, 48:3 (1999), 540
V. Ya. Sosnovskikh, M. Yu. Mel'nikov, I. A. Kovaleva, “Interactions of aliphatic β-amino-β-trifluoromethylvinyl ketones with ethylenediamine”, Russ Chem Bull, 47:11 (1998), 2234
V. YA. SOSNOVSKIKH, M. YU. MEL'NIKOV, “ChemInform Abstract: Unexpected Synthesis of 2‐(3‐Hydroxymethyl‐3,3‐pentamethyleneacetonyl) ‐2‐trifluoromethylimidazolidine.”, ChemInform, 29:30 (1998)