Abstract:
(3,5-Diphenyl-1-o-tolyl-1H-pyrrol-2-yl)phenylmethanone 3a and (1-naphthalen-1-yl-3,5-diphenyl-1H-pyrrol-2-yl)phenylmethanone 4a are atropisomeric and their LAH reductions afford mixtures of atropdiastereoisomeric (3,5-diphenyl-1-o-tolyl-1H-pyrrol-2-yl)- phenylmethanoles 3b,c and (1-naphthalen-1-yl-3,5-diphenyl-1H-pyrrol-2-yl)phenylmethanoles 4b,c, respectively.
Document Type:
Article
Language: English
Citation:
R. Pohl, J. Pawlas, S. Boehm, R. Hrabal, H. Dvorakova, J. Kuthan, “Atropisomeric and atropdiastereoisomeric 2-substituted 1-aryl-3,5-diphenylpyrroles”, Mendeleev Commun., 9:2 (1999), 74–76
Linking options:
https://www.mathnet.ru/eng/mendc4532
https://www.mathnet.ru/eng/mendc/v9/i2/p74
This publication is cited in the following 3 articles:
Ibon Alkorta, José Elguero, Christian Roussel, Nicolas Vanthuyne, Patrick Piras, Advances in Heterocyclic Chemistry, 105, 2012, 1
Robert Klvaňa, Radek Pohl, Jan Pawlas, Jan Čejka, Hana Dvořáková, Richard Hrabal, Stanislav Böhm, Bohumil Kratochvíl, Josef Kuthan, “Sterically Crowded Heterocycles. XII. Atropisomerism of (1-Aryl-3,5-diphenyl-1H-pyrrol-2-yl)(phenyl)methanones”, Collect. Czech. Chem. Commun., 65:5 (2000), 651
Dean A. Frey, Caiming Duan, Ion Ghiviriga, Tomáš Hudlický, “Comparison of Approaches to ent-Morphine via Radical, Cationic, and Heck-Type Cyclizations”, Collect. Czech. Chem. Commun., 65:4 (2000), 561
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