Abstract:
The heterocyclization of N,N’-diarylformamidines with phosphorus trichloride to form 1,4,2,5-diazadiphosphorinanes was found to proceed via the key stage of aliphatic electrophilic ylide substitution at the formamidine carbon atom.
Document Type:
Article
Language: English
Citation:
G. V. Oshovsky, A. M. Pinchuk, A. N. Chernega, I. I. Pervak, A. A. Tolmachev, “Novel heterocyclizations of N,N’-diarylformamidines: 1,4,2,5-diazadiphosphorinanes”, Mendeleev Commun., 9:1 (1999), 38–40
Linking options:
https://www.mathnet.ru/eng/mendc4517
https://www.mathnet.ru/eng/mendc/v9/i1/p38
This publication is cited in the following 3 articles:
Gennady V. Oshovsky, Maria Zablocka, Carine Duhayon, Jean-Pierre Majoral, Anne-Marie Caminade, “Versatile Reactivity of Cyclic 1,2-Dimethylhydrazinodiphosphines”, Z. Anorg. Allg. Chem., 643:14 (2017), 903
Gennady V. Oshovsky, Alexander M. Pinchuk, Alexander N. Chernega, Igor I. Pervak, Andrey A. Tolmachev, “ChemInform Abstract: Novel Heterocyclizations of N,N′‐Diarylformamidines: 1,4,2,5‐Diazadiphosphorinanes.”, ChemInform, 30:29 (1999)
G. V. Oshovsky, A. M. Pinchuk, A. A. Tolmachev, “Amidine function in constructing novel types of phosphorus-containing heterocycles”, Mendeleev Commun., 9:4 (1999), 161–162
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