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Mendeleev Communications, 2000, Volume 10, Issue 1, Pages 20–21
DOI: https://doi.org/10.1070/MC2000v010n01ABEH001168
(Mi mendc4361)
 

This article is cited in 7 scientific papers (total in 7 papers)

Photoinduced activation of arene C–H bonds with (η5-cyclopentadienyl)-trimethylplatinum(IV): a possible role of CpPtR2H

A. N. Vedernikov, S. V. Borisoglebski, A. B. Solomonov, B. N. Solomonov

Department of Chemistry, V.I. Ul'yanov-Lenin Kazan State University, Kazan, Russian Federation
Full-text PDF (82 kB) Citations (7)
Abstract:5-Cyclopentadienyl)trimethylplatinum(IV) reacts with ArMe arenes rather than alkanes or benzene under heating to 150 °C in the dark or under irradiation with light at room temperature by a radical mechanism to produce (η5-cyclopentadienyl)dimethyl-(arylmethyl)platinum(IV) complexes, and the expected complex CpPtR2(H) is unstable under the reaction conditions, as found by the reduction of CpPtMe2I with complex metal hydrides.
Document Type: Article
Language: English


Citation: A. N. Vedernikov, S. V. Borisoglebski, A. B. Solomonov, B. N. Solomonov, “Photoinduced activation of arene C–H bonds with (η5-cyclopentadienyl)-trimethylplatinum(IV): a possible role of CpPtR2H”, Mendeleev Commun., 10:1 (2000), 20–21
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  • https://www.mathnet.ru/eng/mendc/v10/i1/p20
  • This publication is cited in the following 7 articles:
    1. Weifu Zhang, Guo Jiang, Kai Liao, “Synthesis of a Novel Platinum Catalyst and Its Application in the Photoactivated Hydrosilylation Reaction”, Silicon, 16:15 (2024), 5613  crossref
    2. Patrick R. Nimax, Nils Rotthowe, Florian Zoller, Tobias Blockhaus, Fritz Wagner, Dina Fattakhova, Karlheinz Sünkel, “Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide”, Dalton Trans., 50:47 (2021), 17643  crossref
    3. Lei Zhu, Veeranna Yempally, Derek Isrow, Perry J. Pellechia, Burjor Captain, “Radical Exchanges and Structural Transformations on the Iron Carbonyl-Bulky Tin Cluster Complex, Fe2(μ-SnBu 2 t )2(CO)8 by Solvents Toluene, Xylenes and Ethylbenzene”, J Clust Sci, 23:3 (2012), 627  crossref
    4. Lei Zhu, Veeranna Yempally, Derek Isrow, Perry J. Pellechia, Burjor Captain, “Selective benzylic C–H activation of solvent toluene and m-xylene by an iron–tin cluster complex: Fe2(μ-)2(CO)8”, Journal of Organometallic Chemistry, 695:1 (2010), 1  crossref
    5. J. Forniés, E. Lalinde, Comprehensive Organometallic Chemistry III, 2007, 611  crossref
    6. Vladimir Jakubek, Alistair J. Lees, “Quantitative Photochemistry of Cp'Pt(CH3)3 (Cp' = η5-C5H4CH3) in Solution:  A Highly Efficient Organometallic Photoinitiator for Hydrosilylation”, Inorg. Chem., 43:22 (2004), 6869  crossref
    7. Nicola Oberbeckmann, Klaus Merz, Roland A. Fischer, “Coordination of Donor-Functionalized Cyclopentadienyl Ligands at Platinum(II) Centers:  Syntheses and Molecular Structure of [μ-(1,2- η2:5,6-η2-cod){(η5-C5Me4CH2CH2NMe2)MePt}2]”, Organometallics, 20:15 (2001), 3265  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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