Abstract:
A new cubane cluster [Cu4I4(AsAn3)4] was synthesized in 82% yield by the reaction of tris(p-anisyl)arsine (AsAn3) with CuI. At ambient temperature, this cluster exhibits bright yellow-green phosphorescence (λmax = 546 nm) with the quantum yield of 35% and 4.1 μs decay time.
Citation:
Ya. V. Demyanov, M. I. Rakhmanova, I. Yu. Bagryanskaya, A. V. Artem'ev, “Cu4I4-cubane cluster based on tris(p-anisyl)arsine: Synthesis, crystal structure and photophysical properties”, Mendeleev Commun., 33:4 (2023), 484–486
Linking options:
https://www.mathnet.ru/eng/mendc435
https://www.mathnet.ru/eng/mendc/v33/i4/p484
This publication is cited in the following 4 articles:
Sofia V. Skvortsova, Nikita A. Shekhovtsov, Marianna I. Rakhmanova, Denis G. Samsonenko, Elena B. Nikolaenkova, Mark B. Bushuev, “Copper(I) complexes with a 4-(1H-pyrazol-1-yl)-2-(pyridin-2-yl)pyrimidine ligand: Synthesis, structures and theoretical insights into the tuning of emission properties”, Inorganic Chemistry Communications, 174 (2025), 114048
Yan V. Demyanov, Zihao Ma, Zhenglin Jia, Marianna I. Rakhmanova, Gia M. Carignan, Irina Yu. Bagryanskaya, Veronika S. Sulyaeva, Anastasiya A. Globa, Valery K. Brel, Lingqiang Meng, Hong Meng, Qianqian Lin, Jing Li, Alexander V. Artemev, “Copper(I)‐Arsine Clusters with a Near‐Unity Phosphorescence Quantum Yield for X‐Ray Scintillation and LED Applications”, Advanced Optical Materials, 12:14 (2024)
Ya. V. Demyanov, I. Yu. Bagryanskaya, A. V. Artem'ev, “CuI and AgI scorpionate-like complexes based on sterically hindered tris(6-methyl-2-pyridyl)phosphine oxide”, Mendeleev Commun., 34:6 (2024), 812–814
I. D. Strelnik, I. E. Kolesnikov, A. A. Kalinichev, T. P. Gerasimova, K. D. Akhmadgaleev, I. R. Dayanova, A. A. Karasik, “Is dual emission of copper subgroup d10-metal complexes a necessary and sufficient condition for ratiometric luminescence thermometry?”, Mendeleev Commun., 34:4 (2024), 457–471
Contact us: