Abstract:
1,2-Dimethyl-3-(3,3-diethoxypropyn-1-yl)-and 1,2-dimethyl-3-(3-hydroxymethyl-3-methylbutyn-1-yl)diaziridines have been synthesised by the interaction of 4,4-diethoxybutyn-2-al and 4-hydroxymethyl-4-methylpentyn-2-al, respectively, with equimolar amounts of MeNH2 and MeNHCl (or MeNHOSO3H) at pH 9.5–10; the use of an excess of an amine in reactions with 4,4-diethoxybutyn-2-al resulted in a mixture of isomeric 5(3)-diethoxymethyl-1-methylpyrazoles and a mixture of Z/E isomers of 1-cyano- 3,3-diethoxy-2-methylaminoprop-1-enes.
Document Type:
Article
Language: English
Citation:
N. N. Makhova, N. G. Kamalova, Yu. A. Strelenko, “Synthesis of the first representatives of 3-ethynyldiaziridines”, Mendeleev Commun., 11:6 (2001), 227–229
Linking options:
https://www.mathnet.ru/eng/mendc4308
https://www.mathnet.ru/eng/mendc/v11/i6/p227
This publication is cited in the following 3 articles:
Karine A. Eliazyan, Frunze V. Avetisyan, Tamara L. Jivanshiryan, Vergush A. Pivazyan, Emma A. Ghazaryan, Lusya V. Shahbazyan, Siranush V. Harutyunyan, Aleksandr P. Yengoyan, “Synthesis and fungicidal activity of novel 1,3‐disubstituted 1H‐diazirine derivatives”, Journal of Heterocyclic Chem, 48:1 (2011), 118
Géza Stájer, Pál Sohár, Antal Csámpai, Reijo Sillanpää, Ferenc Fülöp, “Preparation and Structure of Bicycloalkane-Condensed Aryldiaziridines Accompanied by Pyrimidines”, HETEROCYCLES, 71:6 (2007), 1315
Nina N. Makhova, Nailya G. Kamalova, Yurii A. Strelenko, “ChemInform Abstract: Synthesis of the First Representatives of 3‐Ethynyldiaziridines.”, ChemInform, 33:23 (2002)
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