Abstract:
The oxidation of Eu(FOD)3 and Eu(TTA)3 (FOD is heptafluorodimethyloctanedionate and TTA is thenoyltrifluoroacetonate) by dimethyldioxirane (DMD) is accompanied by chemiluminescence; the excitation of europium(III) occurs due to an energy released upon oxidation of the ligands.
Document Type:
Article
Language: English
Citation:
G. Ya. Maistrenko, O. A. Kotchneva, R. P. Latypova, V. P. Kazakov, “Chemiluminescence in the oxidation of europium β-diketonates by dimethyldioxirane”, Mendeleev Commun., 11:5 (2001), 188–190
Linking options:
https://www.mathnet.ru/eng/mendc4286
https://www.mathnet.ru/eng/mendc/v11/i5/p188
This publication is cited in the following 3 articles:
Gulshat A. Masyagutova, Alexander V. Mamykin, Sergey L. Khursan, “Ligand-assisted excitation of Eu(III) during interaction of Eu(FOD)3 with xenon difluoride in acetonitrile solution”, Journal of Fluorine Chemistry, 275 (2024), 110270
K.S. Smirnova, E.A. Ivanova, T.S. Sukhikh, I.P. Pozdnyakov, V.V. Dotsenko, E.V. Lider, “Luminescent properties of Ln(III) complexes with 2-[(phenylamino)methylene]-5,5-dimethyl-cyclohexane-1,3-dione as an antenna”, Inorganica Chimica Acta, 525 (2021), 120490
Waldemar Adam, Cong‐Gui Zhao, Kavitha Jakka, Oxidation of Organic Compounds by Dioxiranes, 2009, 311
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