Abstract:
First electronic absorption spectra of quintet and septet nitrenes were recorded during the photolysis of 4-amino-2,6-diazido-3,5-dichloropyridine and 2,4,6-triazido-3,5-dichloropyridine in frozen solution matrices at 77 K.
Document Type:
Article
Language: English
Citation:
S. V. Chapyshev, “Electronic absorption spectra of quintet and septet pyridylnitrenes”, Mendeleev Commun., 12:5 (2002), 168–170
Linking options:
https://www.mathnet.ru/eng/mendc4146
https://www.mathnet.ru/eng/mendc/v12/i5/p168
This publication is cited in the following 21 articles:
Sergei V. Chapyshev, Enrique Mendez‐Vega, Wolfram Sander, “Molecular Magnets: The Synthesis and Characterization of High‐Spin Nitrenes”, Chemistry A European J, 27:4 (2021), 1258
S. V. Chapyshev, D. V. Korchagin, E. Ya. Misochko, “Recent advances in chemistry of high-spin nitrenes”, Russian Chem. Reviews, 90:1 (2021), 39–69
Silvia E. Loredo-Carrillo, Elisa Leyva, Matthew S. Platz, Agobardo Cárdenas-Chaparro, Antonio Martínez-Richa, “Thermolysis of 2-azido-3-(R-anilino)-1,4-naphthoquinones. Nitrene insertion versus hydrogen abstraction”, Tetrahedron Letters, 61:14 (2020), 151731
Sergei V. Chapyshev, Denis V. Korchagin, Paolo Costa, Wolfram Sander, “Photochemical generation of high-spin nitrenes from 4,6-diazido-N-(4,6-diazido-1,3,5-triazin-2-yl)-1,3,5-triazin-2-amine in solid argon”, Journal of Photochemistry and Photobiology A: Chemistry, 377 (2019), 207
Enrique Mendez‐Vega, Joel Mieres‐Perez, Sergei V. Chapyshev, Wolfram Sander, “Persistent Organic High‐Spin Trinitrenes”, Angew Chem Int Ed, 58:37 (2019), 12994
Enrique Mendez‐Vega, Joel Mieres‐Perez, Sergei V. Chapyshev, Wolfram Sander, “Persistent Organic High‐Spin Trinitrenes”, Angewandte Chemie, 131:37 (2019), 13128
Sergei Chapyshev, “Six-Membered Aromatic Polyazides: Synthesis and Application”, Molecules, 20:10 (2015), 19142
Christopher Finke, Dirk Grote, Rüdiger W. Seidel, Sergei V. Chapyshev, Wolfram Sander, “Matrix isolation and IR spectroscopic characterization of 3,5‐difluoropyridyl‐2,4,6‐trinitrene”, J of Physical Organic Chem, 25:6 (2012), 486
S. V. Chapyshev, “Aromatic polyazides and high-spin nitrenes”, Russ Chem Bull, 60:7 (2011), 1274
Kenji Sugisaki, Kazuo Toyota, Kazunobu Sato, Daisuke Shiomi, Masahiro Kitagawa, Takeji Takui, “Spin–Orbit Contributions in High‐Spin Nitrenes/Carbenes: A Hybrid CASSCF/MRMP2 Study of Zero‐Field Splitting Tensors”, ChemPhysChem, 11:14 (2010), 3146
Sergei V. Chapyshev, Eugenii Ya. Misochko, Alexander V. Akimov, Viktor G. Dorokhov, Patrik Neuhaus, Dirk Grote, Wolfram Sander, “Molecular Structure and Magnetic Parameters of Septet 2,4,6-Trinitrenotoluene”, J. Org. Chem., 74:19 (2009), 7238
D. V. Korchagin, K. V. Bozhenko, S. V. Chapyshev, S. M. Aldoshin, “A quantum-chemical study on the selectivity of photolysis of azido groups in 2,4,6-triazido-3,5-dichloropyridine”, High Energy Chem, 43:4 (2009), 289
S. V. Chapyshev, V. F. Lavitskii, A. V. Akimov, E. Ya. Misochko, A. V. Shastin, D. V. Korchagin, G. V. Shilov, S. M. Aldoshin, “Photochemical generation of triplet—triplet nitrene pairs in aromatic diazide crystals”, Russ Chem Bull, 57:3 (2008), 524
E. Ya. Misochko, A. V. Akimov, S. V. Chapyshev, “High resolution electron paramagnetic resonance spectroscopy of septet pyridyl-2,4,6-trinitrene in solid argon: Fine-structure parameters of six electron-spin cluster”, The Journal of Chemical Physics, 129:17 (2008)
S. I. Kuzina, A. I. Mikhailov, S. V. Chapyshev, “Radiolysis and photolysis of crystalline 2,4,6-triazido-3,5-dichloropyridine: Generation of Quintet dinitrenes”, High Energy Chem, 41:4 (2007), 245
R. B. Morgunov, V. L. Berdinskii, M. V. Kirman, Y. Tanimoto, S. V. Chapyshev, “Photochemical magnetism of crystalline 2,4,6-triazido-3,5-dichloropyridine”, High Energy Chem, 41:1 (2007), 33
M. F. Budyka, “Photochemistry of aromatic azides and nitrenes”, High Energy Chem, 41:3 (2007), 176
Kenji Sugisaki, Kazuo Toyota, Kazunobu Sato, Daisuke Shiomi, Takeji Takui, “Ab Initio MO Analysis of the Excited Electronic States of High‐Spin Quintet 2‐Methylphenylene‐1,3‐dinitrene”, Angewandte Chemie, 118:14 (2006), 2315
Kenji Sugisaki, Kazuo Toyota, Kazunobu Sato, Daisuke Shiomi, Takeji Takui, “Ab Initio MO Analysis of the Excited Electronic States of High‐Spin Quintet 2‐Methylphenylene‐1,3‐dinitrene”, Angew Chem Int Ed, 45:14 (2006), 2257
Sergei V. Chapyshev, Richard Walton, Paul R. Serwinski, Paul M. Lahti, “Quintet State Electron Spin Resonance Spectra of Pyridyldinitrenes”, J. Phys. Chem. A, 108:32 (2004), 6643
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