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Mendeleev Communications, 2023, Volume 33, Issue 3, Pages 411–412
DOI: https://doi.org/10.1016/j.mencom.2023.04.035 (Mi mendc412) 		 
This article is cited in 1 scientific paper (total in 1 paper)

Communications

Effect of ethanol solution of iodine on degradation of poly(ε-caprolactone)

M. A. Khavpachevab, E. S. Trofimchukb, A. A. Puchkovc, V. A. Deminaac, N. G. Sedushac, N. I. Nikonorovab, S. I. Balobanovab, S. N. Chvalunac

a N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
c National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
Full-text PDF (295 kB) Citations (1)
DOI: https://doi.org/10.1016/j.mencom.2023.04.035
Abstract: The study of the effect of iodine on the degradation of poly(ε-caprolactone) fibers has revealed a drastic decrease in their molecular weight upon 24 h exposure to a 10% iodine solution in ethanol. It has been assumed that the main mechanism of this degradation is alcoholysis which proceeds with an efficient rate constant of nearly 7.5 × 10–3 h–1
Keywords: poly(ε-caprolactone), fibers, iodine, ethanol, degradation, alcoholysis.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (873.5 Kb)


Citation: M. A. Khavpachev, E. S. Trofimchuk, A. A. Puchkov, V. A. Demina, N. G. Sedush, N. I. Nikonorova, S. I. Balobanova, S. N. Chvalun, “Effect of ethanol solution of iodine on degradation of poly(ε-caprolactone)”, Mendeleev Commun., 33:3 (2023), 411–412
Linking options:
  • https://www.mathnet.ru/eng/mendc412
  • https://www.mathnet.ru/eng/mendc/v33/i3/p411
    • This publication is cited in the following 1 articles:
    1. E. S. Trofimchuk, S. I. Balobanova, A. A. Puchkov, A. A. Piryazev, N. G. Sedush, N. I. Nikonorova, I. D. Kovtun, S. N. Chvalun, Mendeleev Commun., 35:2 (2025), 208–210  mathnet  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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