Abstract:
The method of voltammetric time-resolved waves (TRW) based on a comparative analysis of experimental and simulated curves of photoemissionally generated intermediates was used to determine the thermodynamic and kinetic properties of the R/R− redox pairs for the benzyl PhCH2⋅ and benzhydryl Ph2CH⋅ radicals.
Document Type:
Article
Language: English
Citation:
A. G. Krivenko, V. A. Kurmaz, A. S. Kotkin, “Prospects for the determination of thermodynamic and kinetic parameters of electrode reaction intermediates by laser photoemission”, Mendeleev Commun., 12:1 (2002), 11–14
Linking options:
https://www.mathnet.ru/eng/mendc4068
https://www.mathnet.ru/eng/mendc/v12/i1/p11
This publication is cited in the following 9 articles:
A. S. Mendkovich, A. I. Rusakov, “REACTIVITY OF ANION RADICAL AND DIANION OF ORGANIC COMPOUNDS (REVIEW)”, Èlektrohimiâ, 59:12 (2023), 753
A. S. Mendkovich, A. I. Rusakov, “Reactivity of Radical Anions and Dianions of Organic Compounds: A Review”, Russ J Electrochem, 59:12 (2023), 999
V. A. Kurmaz, A. S. Kotkin, G. V. Simbirtseva, “Investigation of electrochemical behavior of secondary products of capture of OH radicals by dimethyl sulfoxide molecules using laser photoemission”, Moscow Univ. Chem. Bull., 68:6 (2013), 273
David C. Magri, Mark S. Workentin, Encyclopedia of Radicals in Chemistry, Biology and Materials, 2012
Vladimir A. Kurmaz, Alexander S. Kotkin, Galina V. Simbirtseva, “Laser photoemission generation and electrochemical study of methyl radicals as secondary products of OH radicals capture by dimethyl sulfoxide molecules”, J Solid State Electrochem, 15:10 (2011), 2119
A. G. Krivenko, V. A. Kurmaz, “Thermodynamic and kinetic characteristics of intermediates of electrode reactions. Comparative laser photoemission study of the kinetics of electron transfer for certain alkylaryl and alkylhalide radicals”, Russ J Electrochem, 42:2 (2006), 111
A. G. Krivenko, A. S. Kotkin, V. A. Kurmaz, “Thermodynamic and kinetic characteristics of intermediates of electrode reactions: Determination by direct and combined electrochemical methods”, Russ J Electrochem, 41:2 (2005), 122
A. G. Krivenko, A. S. Kotkin, V. A. Kurmaz, “Thermodynamic and kinetic characteristics of intermediates of electrode reactions: A comparative investigation of a number of alkylaryl and alkyl halide radicals by the laser photoemission methods”, Russ J Electrochem, 41:2 (2005), 137
Alexander G Krivenko, Alexander S Kotkin, Vladimir A Kurmaz, “Mechanism of electroreduction of intermediates with and without a proton donor”, Electrochimica Acta, 47:24 (2002), 3891
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