Abstract:
Pentaphosphaferrocenes were prepared in good yields by the reaction of the pentaphospholide anion P5− with half-sandwich complexes of iron containing carbonyl groups or tertiary phosphine ligands.
Document Type:
Article
Language: English
Citation:
V. A. Miluykov, O. G. Sinyashin, O. Scherer, E. Hey-Hawkins, “Reactions of the pentaphospholide anion with half-sandwich complexes of iron: a new route to pentaphosphaferrocenes”, Mendeleev Commun., 12:1 (2002), 1–2
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https://www.mathnet.ru/eng/mendc4063
https://www.mathnet.ru/eng/mendc/v12/i1/p1
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Nilmadhab Roy, Rishav Das, Rupankar Paira, Priyankar Paira, “Different routes for the construction of biologically active diversely functionalized bicyclo[3.3.1]nonanes: an exploration of new perspectives for anticancer chemotherapeutics”, RSC Adv., 13:32 (2023), 22389
Zi-Chuan Wang, Lei Qiao, Zhong-Ming Sun, Manfred Scheer, “Inorganic Ferrocene Analogue [Fe(P4)2]2–”, J. Am. Chem. Soc., 144:15 (2022), 6698
Stephan Reichl, Eric Mädl, Felix Riedlberger, Martin Piesch, Gábor Balázs, Michael Seidl, Manfred Scheer, “Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus”, Nat Commun, 12:1 (2021)
Christoph Riesinger, Gábor Balázs, Michael Bodensteiner, Manfred Scheer, “Stabilization of Pentaphospholes as η5‐Coordinating Ligands”, Angew Chem Int Ed, 59:52 (2020), 23879
Christoph Riesinger, Gábor Balázs, Michael Bodensteiner, Manfred Scheer, “Stabilisierung von Pentaphospholen als η5‐koordinierende Liganden”, Angewandte Chemie, 132:52 (2020), 24088
I. A. Bezkishko, A. A. Zagidullin, V. A. Milyukov, O. G. Sinyashin, “Alkali and transition metals phospholides”, Russian Chem. Reviews, 83:6 (2014), 555–574
Maria Caporali, Luca Gonsalvi, Andrea Rossin, Maurizio Peruzzini, “P4 Activation by Late-Transition Metal Complexes”, Chem. Rev., 110:7 (2010), 4178
Tatyana P. Gryaznova, Sergey A. Katsyuba, Vasiliy A. Milyukov, Oleg G. Sinyashin, “DFT study of substitution effect on the geometry, IR spectra, spin state and energetic stability of the ferrocenes and their pentaphospholyl analogues”, Journal of Organometallic Chemistry, 695:24 (2010), 2586
A.J. Phillips, J.A. Henderson, K.L. Jackson, Comprehensive Heterocyclic Chemistry III, 2008, 337
Vasily Miluykov, Alexandr Kataev, Oleg Sinyashin, Evamarie Hey-Hawkins, “The Chemical Properties of Alkali Metals Heptaphosphides”, Phosphorus, Sulfur, and Silicon and the Related Elements, 183:2-3 (2008), 509
V. A. Milyukov, E. Hey-Hawkins, O. G. Sinyashin, “Reactions of sodium pentaphosphacyclopentadienide with half-sandwich iron complexes”, Russ Chem Bull, 56:3 (2007), 549
Vasili Miluykov, Alexander Kataev, Oleg Sinyashin, Peter Lönnecke, Evamarie Hey‐Hawkins, “Facile Routes to Sodium Tetradecaphosphide Na4P14 and Molecular Structure of Na4(DME)7.5P14 and Na4(en)6P14 (DME = 1,2‐dimethoxyethane; en = ethylenediamine)”, Zeitschrift anorg allge chemie, 632:10-11 (2006), 1728
François Mathey, “Phospha‐Organic Chemistry: Panorama and Perspectives”, Angew Chem Int Ed, 42:14 (2003), 1578
V. A. Miluykov, O. G. Sinyashin, P. Lönnecke, E. Hey-Hawkins, “Unexpected formation of triple-deckers: bis(cyclopentadienyliron)-μ:η4:4-tetraphosphabutadiene complexes”, Mendeleev Commun., 13:5 (2003), 212–213
Vasily A. Miluykov, Oleg G. Sinyashin, Otto Scherer, Evamarie Hey‐Hawkins, “ChemInform Abstract: Reactions of the Pentaphospholide Anion with Half‐Sandwich Complexes of Iron: A New Route to Pentaphosphaferrocenes.”, ChemInform, 33:31 (2002)
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