Abstract:
Racemic (π-pentamethylcyclopentadienyl)(2,2,2-trifluoro-1-phenylethyl diethylphosphinite)rhodium dichloride 2 was found to be a conglomerate, which undergoes spontaneous resolution during crystallization.
Document Type:
Article
Language: English
Citation:
I. L. Odinets, O. I. Artyushin, E. V. Sharova, E. I. Goryunov, D. G. Golovanov, K. A. Lyssenko, P. V. Petrovskii, T. A. Mastryukova, “Generation of an optically active rhodium(III) complex by crystallization-induced spontaneous resolution of a racemic mixture”, Mendeleev Commun., 13:3 (2003), 102–104
Linking options:
https://www.mathnet.ru/eng/mendc3975
https://www.mathnet.ru/eng/mendc/v13/i3/p102
This publication is cited in the following 6 articles:
Vladislava V. Matveevskaya, Dmitry I. Pavlov, Andrei S. Potapov, “Iridium(III) and Rhodium(III) Half-Sandwich Coordination Compounds with 11H-Indeno[1,2-b]quinoxalin-11-one Oxime: A Case of Spontaneous Resolution of Rh(III) Complex”, Inorganics, 10:11 (2022), 179
Chote Lal Yadav, Gunjan Rajput, Kamal Kumar Bisht, Michael G. B. Drew, Nanhai Singh, “Spontaneous Resolution upon Crystallization and Preferential Induction of Chirality in a Discrete Tetrahedral Zinc(II) Complex Comprised of Achiral Precursors”, Inorg. Chem., 58:21 (2019), 14449
M. Nieuwenhuyzen, G. C. Saunders, “Crystal structure of (η5-pentamethylcyclo-pentadienyl)(methyldiphenylphosphite-P)dichlororhodium(III)”, J Struct Chem, 54:1 (2013), 264
Lluïsa Pérez-García, David B. Amabilino, “Spontaneous resolution, whence and whither: from enantiomorphic solids to chiral liquid crystals, monolayers and macro- and supra-molecular polymers and assemblies”, Chem. Soc. Rev., 36:6 (2007), 941
Oleg Artyushin, Irina Odinets, Evgenii Goryunov, Ivan Fedyanin, Konstantin Lyssenko, Tatyana Mastryukova, Gerd-Volker Röschenthaler, Tamás Kégl, György Keglevich, László Kollár, “α-Fluorinated cyclic amidophosphite ligands. Their synthesis, Rh complexes and catalytic activity in the hydroformylation of styrene”, Journal of Organometallic Chemistry, 691:26 (2006), 5547
Irina Odinets, Tamás Kégl, Elena Sharova, Oleg Artyushin, Evgenii Goryunov, Galina Molchanova, Konstantin Lyssenko, Tatyana Mastryukova, Gerd-Volker Röschenthaler, György Keglevich, László Kollár, “Novel α-fluorinated cyclic phosphite and phosphinite ligands and their Rh-complexes as suitable catalysts in hydroformylation”, Journal of Organometallic Chemistry, 690:14 (2005), 3456
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