Abstract:
The interaction of citral 6,7-epoxides with acetonitrile catalysed by sulfuric acid results in the formation of substituted 2-oxazolines without affecting the aldehyde group of citral, whereas the interaction of citral 2,3-epoxides with acetone and acetonitrile results in the formation of bicyclic and tricyclic compounds.
Document Type:
Article
Language: English
Citation:
O. I. Yarovaya, D. V. Korchagina, O. V. Salomatina, M. P. Polovinka, V. A. Barkhash, “Synthesis of heterocyclic compounds in acid-catalysed reactions of citral epoxides”, Mendeleev Commun., 13:1 (2003), 27–29
Linking options:
https://www.mathnet.ru/eng/mendc3941
https://www.mathnet.ru/eng/mendc/v13/i1/p27
This publication is cited in the following 4 articles:
Eman M. Elgendy, Manal Y. Semeih, “Phyto – Monoterpene linalool as precursor to synthesis epoxides and hydroperoxides as anti carcinogenic agents via thermal and photo chemical oxidation reactions”, Arabian Journal of Chemistry, 12:7 (2019), 966
Amna A. Saddiq, Suzan A. Khayyat, “Chemical and antimicrobial studies of monoterpene: Citral”, Pesticide Biochemistry and Physiology, 98:1 (2010), 89
E. M. Elgendy, S. A. Khayyat, “Oxidation studies on some natural monoterpenes: Citral, pulegone, and camphene”, Russ J Org Chem, 44:6 (2008), 814
Olga I. Yarovaya, Dina V. Korchagina, Oksana V. Salomatina, Marina P. Polovinka, Vladimir A. Barkhash, “Synthesis of Heterocyclic Compounds in Acid‐Catalyzed Reactions of Citral Epoxides.”, ChemInform, 34:32 (2003)
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