P. V. Novikov, O. R. Malyshev, K. A. Lyssenko, R. G. Kostyanovsky, “Resolution and racemization of nonbenzenoid atropenantiomers”, Mendeleev Commun., 14:6 (2004), 310

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Mendeleev Communications, 2004, Volume 14, Issue 6, Pages 310–312
DOI: https://doi.org/10.1070/MC2004v014n06ABEH002049 (Mi mendc3923)

This article is cited in 1 scientific paper (total in 1 paper)

Resolution and racemization of nonbenzenoid atropenantiomers

P. V. Novikov^a, O. R. Malyshev^b, K. A. Lyssenko^c, R. G. Kostyanovsky^a

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

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DOI: https://doi.org/10.1070/MC2004v014n06ABEH002049

Abstract: The three-step synthesis of adduct 3 has been reinvestigated; enantiomers 3a and 3b have been separated by enantioselective chromatography and the racemization barrier of 3a was determined as ΔG^≠ = 24.4 kcal mol⁻¹ (16 °C).

Document Type: Article

Language: English

Citation: P. V. Novikov, O. R. Malyshev, K. A. Lyssenko, R. G. Kostyanovsky, “Resolution and racemization of nonbenzenoid atropenantiomers”, Mendeleev Commun., 14:6 (2004), 310–312

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https://www.mathnet.ru/eng/mendc/v14/i6/p310

This publication is cited in the following 1 articles:

Citing articles in Google Scholar: Russian citations, English citations
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