Abstract:
The reaction of 2-acetyl-5-methyl-2H-1,2,3-diazaphosphole with (rac)-butane-2,3-diol at temperatures below 0 °C leads to the formation of a hydrospirophosphorane containing both a diazaphospholene and a dioxaphospholane ring system and a β-hydroxyalkoxy-1,2,3-diazaphospholene. On heating, these products form a hydrospirotetraoxaphosphorane, its tautomeric monocyclic β-hydroxyalkylphosphite and N-acetyl-N’-isopropylidene-hydrazine.
Document Type:
Article
Language: English
Citation:
N. G. Khusainova, O. A. Mostovaya, N. M. Azancheev, I. A. Litvinov, D. B. Krivolapov, R. A. Cherkasov, “Reaction of 2-acetyl-5-methyl-2H-1,2,3-diazaphosphole with butane-2,3-diol”, Mendeleev Commun., 14:5 (2004), 212–214
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https://www.mathnet.ru/eng/mendc3881
https://www.mathnet.ru/eng/mendc/v14/i5/p212
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N. G. Khusainova, O. A. Mostovaya, M. A. Khusainov, S. A. Slivko, “Reaction of a 2H-1,2,3-Diazaphosphole with Ethane-1,2-Dithiol”, Phosphorus, Sulfur, and Silicon and the Related Elements, 188:1-3 (2013), 45
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Wagee A. Yehye, Azhar Ariffin, Seik Weng Ng, “2-[(3,5-Di-tert-butyl-4-hydroxybenzyl)sulfanyl]-N′-isopropylideneacetohydrazide”, Acta Crystallogr E Struct Rep Online, 65:4 (2009), o730
V.V. Zhdankin, Comprehensive Heterocyclic Chemistry III, 2008, 583
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N. G. Khusainova, O. A. Mostovaya, R. A. Cherkasov, “Reaction of 2H-1,2,3-diazaphosphole with ethanolamine”, Russ J Gen Chem, 76:3 (2006), 495
Narkis G. Khusainova, Olga A. Mostovaya, Nail M. Azancheev, Igor A. Litvinov, Dmitry B. Krivolapov, Rafael A. Cherkasov, “Reaction of 2‐Acetyl‐5‐methyl‐2H‐1,2,3‐diazaphosphole with Butane‐2,3‐diol.”, ChemInform, 36:9 (2005)
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