Abstract:
The electrochemistry of the macrocyclic dicopper(II) and dinickel(II) complexes [M2L]Cl2, where L is the [2+2] condensation product of 1,3-diaminopropane and 2,6-diformyl-4-tert-butylphenol, is reported in relation to hydrogen peroxide electrocatalysis on mercury. The opposite effects observed with [Cu2L]Cl2 (inhibition) and [Ni2L]Cl2 (enhancement) are explained by different reduction mechanisms.
Document Type:
Article
Language: English
Citation:
N. V. Roznyatovskaya, G. A. Tsirlina, V. V. Roznyatovskii, A. S. Mitiaev, Y. D. Smurnyy, “Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis”, Mendeleev Commun., 15:3 (2005), 93–95
Linking options:
https://www.mathnet.ru/eng/mendc3692
https://www.mathnet.ru/eng/mendc/v15/i3/p93
This publication is cited in the following 3 articles:
Alexander G. Krivenko, Alexander S. Kotkin, Galina V. Simbirtseva, Renat R. Nazmutdinov, Dmitry V. Glukhov, Nataliya V. Roznyatovskaya, Galina A. Tsirlina, “Binuclear Robson type Ni(ii) complex as a reactant supplementing our knowledge of the orientation effects in electrochemical kinetics”, Phys. Chem. Chem. Phys., 10:17 (2008), 2390
Renat R. Nazmutdinov, Nataliya V. Roznyatovskaya, Dmitrii V. Glukhov, Ibragim Manyurov, Vladimir M. Mazin, Galina A. Tsirlina, Michael Probst, “Medium and Interfacial Effects in the Multistep Reduction of Binuclear Complexes with Robson-Type Ligand”, Inorg. Chem., 47:15 (2008), 6659
Nataliya V. Roznyatovskaya, Veronika K. Laurinavichute, Galina A. Tsirlina, Vladimir M. Mirsky, “Electrochemistry and catalytic behavior of immobilized binuclear complexes of copper(II) and nickel(II) with Robson type ligand”, J Solid State Electrochem, 11:7 (2007), 981
Contact us: