Abstract:
The interaction of 4,6-di-tert-butyl-1,2,3-benzodithiazolyl (Herz radical) 1 with O2 in a hydrocarbon solution leads to substituted N,N’-disulfinyl-2,2’-diaminodiphenyl disulfide 2, the radical decay kinetics corresponds to a self-termination reaction with a rate constant, which is a linear function of the concentration of dissolved O2.
Document Type:
Article
Language: English
Citation:
A. Yu. Makarov, S. N. Kim, N. P. Gritsan, I. Yu. Bagryanskaya, Yu. V. Gatilov, A. V. Zibarev, “Interaction of 1,2,3-benzodithiazolyls (Herz radicals) with dioxygen”, Mendeleev Commun., 15:1 (2005), 14–17
Linking options:
https://www.mathnet.ru/eng/mendc3655
https://www.mathnet.ru/eng/mendc/v15/i1/p14
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