Abstract:
The interaction of hexachlorocyclopentadiene (CpCl6) with KOH in MeOH followed by acidic treatment of the reaction mass results in synthetically valuable 2,3,5-trichloro-4,4-dimethoxy- or 2,5-dichloro-3,4,4-trimethoxycyclopent-2-en-1-ones.
Document Type:
Article
Language: English
Citation:
N. A. Ivanova, K. S. Kislitsina, M. S. Miftakhov, “Efficient one-pot synthesis of chlorinated cyclopentenones from hexachlorocyclopentadiene”, Mendeleev Commun., 17:5 (2007), 306–307
Linking options:
https://www.mathnet.ru/eng/mendc3468
https://www.mathnet.ru/eng/mendc/v17/i5/p306
This publication is cited in the following 3 articles:
G. A. Tolstikov, S. A. Ismailov, F. A. Gimalova, N. A. Ivanova, M. S. Miftakhov, “Science-intensive utilization of environmentally harmful polychlorocarbons. Synthesis of biologically active cyclopentanoids from hexachlorocyclopentadiene”, Russ Chem Bull, 62:1 (2013), 226
N. A. Ivanova, K. S. Kislitsina, M. S. Miftakhov, “Synthesis of 3,5-dichlorocyclopentane-1,2,4-trione”, Russ J Org Chem, 46:12 (2010), 1885
Nadezhda A. Ivanova, Kseniya S. Kislitsina, Mansur S. Miftakhov, “ChemInform Abstract: Efficient One‐Pot Synthesis of Chlorinated Cyclopentenones from Hexachlorocyclopentadiene.”, ChemInform, 39:9 (2008)
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