Abstract:
A carbon label has been introduced into phthalocyanine molecules in order to perform a correct assignment of signals in the 13C NMR spectra of planar and sandwich-type metal complexes. With europium and lutetium as examples, the introduction of the label and the use of DEPT-135, GATED and 1H–13C COSY procedures enabled the recording and total assignment of signals in the 13C NMR spectra of homo- and heteronuclear three-decked phthalocyanines of rare-earth elements.
Document Type:
Article
Language: English
Citation:
V. E. Pushkarev, E. V. Shulishov, Yu. V. Tomilov, L. G. Tomilova, “The first example of a carbon label for interpreting the 13C NMR spectra of phthalocyanine metal complexes”, Mendeleev Commun., 17:4 (2007), 218–219
Linking options:
https://www.mathnet.ru/eng/mendc3435
https://www.mathnet.ru/eng/mendc/v17/i4/p218
This publication is cited in the following 4 articles:
Kuo‐Hui Wu, Wen‐Chien Huang, Je‐Chuang Wang, Chia‐Ling Li, Tsung‐Han Yang, “Synthesis and Antimicrobial Properties of Silver Phthalocyanine (AgPc)/Ag Supported on Aminosilane‐Modified Silicate”, ChemistrySelect, 9:31 (2024)
Victor E. Pushkarev, Larisa G. Tomilova, Victor N. Nemykin, “Historic overview and new developments in synthetic methods for preparation of the rare-earth tetrapyrrolic complexes”, Coordination Chemistry Reviews, 319 (2016), 110
Kirill P. Birin, Yulia G. Gorbunova, Aslan Yu. Tsivadze, “The approach to the direct interpretation of 13C NMR of heteroleptic triple-decker (porphyrinato)(phthalocyaninato) lanthanum(III) without carbon labeling”, J. Porphyrins Phthalocyanines, 15:07n08 (2011), 667
Victor E. Pushkarev, Alexander Yu. Tolbin, Nataliya E. Borisova, Stanislav A. Trashin, Larisa G. Tomilova, “A3B‐Type Phthalocyanine‐Based Homoleptic Lanthanide(III) Double‐Decker π‐Radical Complexes Bearing Functional Hydroxy Groups: Synthetic Approach, Spectral Properties and Electrochemical Study”, Eur J Inorg Chem, 2010:33 (2010), 5254
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