H. J. Frohn, V. V. Bardin, “Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe]+ salt”, Mendeleev Commun., 17:3 (2007), 137

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Mendeleev Communications, 2007, Volume 17, Issue 3, Pages 137–138
DOI: https://doi.org/10.1016/j.mencom.2007.05.001 (Mi mendc3403)

This article is cited in 4 scientific papers (total in 4 papers)

Distinct reactivities of cis- and trans-R_FCF=CFBF₂ towards XeF₂ and the first synthesis of a [trans-R_FCF=CFXe]⁺ salt

H. J. Frohn^a, V. V. Bardin^b

^a Department of Chemistry, Institute of Inorganic Chemistry, University of Duisburg-Essen, Duisburg, Germany
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Full-text PDF (226 kB) Citations (4)

DOI: https://doi.org/10.1016/j.mencom.2007.05.001

Abstract: The competitive reaction of C₄F₉CF=CFBF₂ (cis : trans = 1.2:1) with XeF₂ demonstrated for the first time a remarkably lower reaction rate of the trans isomer with respect to the cis isomer in the xenodeborylation reaction (formation of the [C₄F₉CF=CFXe]⁺ cation with a cis : trans ratio of 2.5 to 4:1) and allowed us to develop reaction conditions for the syntheses of [trans-C₄F₉CF=CFXe]⁺ salts.

Document Type: Article

Language: English

Citation: H. J. Frohn, V. V. Bardin, “Distinct reactivities of cis- and trans-R_FCF=CFBF₂ towards XeF₂ and the first synthesis of a [trans-R_FCF=CFXe]⁺ salt”, Mendeleev Commun., 17:3 (2007), 137–138

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https://www.mathnet.ru/eng/mendc3403

https://www.mathnet.ru/eng/mendc/v17/i3/p137

This publication is cited in the following 4 articles:

Anton Yu Shabalin, Nicolay Yu Adonin, Vadim V Bardin, “Substitution of fluorine in M[C6F5BF3] with organolithium compounds: distinctions between O- and N-nucleophiles”, Beilstein J. Org. Chem., 13 (2017), 703
Hermann-Josef Frohn, Matthias Giesen, Dirk Welting, Vadim V. Bardin, “Bis(perfluoroorganyl)bromonium salts [(RF)2Br]Y (RF=aryl, alkenyl, and alkynyl)”, Journal of Fluorine Chemistry, 131:9 (2010), 922
Hermann‐Josef Frohn, Vadim V. Bardin, “A Widely Applicable Synthetic Approach to Alk‐1‐yn‐1‐yl(polyfluoroorganyl)‐iodonium Salts [(RC≡C)(R′)I][BF4]”, Zeitschrift anorg allge chemie, 634:1 (2008), 82
Hermann‐Josef Frohn, Vadim V. Bardin, “Reactions of Alk‐1‐enylxenonium(II) and Alk‐1‐ynylxenonium(II) Salts [RXe]Y with Bromides and Iodides in Anhydrous HF”, Zeitschrift anorg allge chemie, 633:10 (2007), 1627

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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