Abstract:
The reactions of [LGa–GaL] (L = dpp-bian = 1,2-bis[(2,6-di-isopropylphenyl)imino]acenaphthene) with ammonia and pyrrolidine in toluene lead to the formation of adducts [L(NH3)Ga–Ga(NH3)L], [L(HNC4H8)Ga–GaL] and [L(HNC4H8)Ga–Ga(HNC4H8)L], respectively. In contrast, the reaction between crystalline digallane and an excess of pyrrolidine leads to the formation of compound [LGa(NC4H8)(HNC4H8)]. The complex [LGa(C5H5N)(μ-O)Ga(C5H5N)L] was obtain from reaction of digallane with N2O in the presence of pyridine.
Citation:
T. S. Koptseva, N. L. Bazyakina, E. V. Baranov, I. L. Fedushkin, “Reactivity of digallane toward nitrogen-containing compounds”, Mendeleev Commun., 33:2 (2023), 167–170
Linking options:
https://www.mathnet.ru/eng/mendc339
https://www.mathnet.ru/eng/mendc/v33/i2/p167
This publication is cited in the following 4 articles:
T. S. Koptseva, E. V. Baranov, I. L. Fedushkin, “3D coordination polymers with N-heterocyclic Ga(I) moieties”, Koordinacionnaâ himiâ, 50:3 (2024)
T. S. Koptseva, E. V. Baranov, I. L. Fedushkin, “3D Coordination Polymers with N-Heterocyclic Ga(I) Moieties”, Russ J Coord Chem, 50:2 (2024), 85
Iakov S. Fomenko, Nikolay F. Romashev, Artem L. Gushchin, “Advances in the chemistry of redox-active bis(imino)acenaphthenes (BIAN): A case of transition metal complexes”, Coordination Chemistry Reviews, 514 (2024), 215845
Tatyana S. Koptseva, Mikhail V. Moskalev, Evgeny V. Baranov, Igor L. Fedushkin, “Reduction of Nitrous Oxide and Binding of Carbon Dioxide by Acenaphthene-1,2-diimine Aluminum Compounds”, Organometallics, 42:10 (2023), 965
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