Abstract:
The asymmetric hydrogenation of methyl levulinate to chiral γ-valerolactone has been performed with the recycling of a RuII–BINAP catalyst deposited on a solid organic polyelectrolyte; enantioselectivity up to 99% ee has been achieved at high conversion of substrate after three recycles of the catalyst.
Document Type:
Article
Language: English
Citation:
E. V. Starodubtseva, O. V. Turova, M. G. Vinogradov, V. A. Ferapontov, I. V. Razmanov, S. G. Zlotin, A. S. Kucherenko, “Asymmetric hydrogenation of the C=O bond with the recycling of an organometal catalyst deposited on a solid organic polyelectrolyte”, Mendeleev Commun., 17:1 (2007), 20–21
Linking options:
https://www.mathnet.ru/eng/mendc3362
https://www.mathnet.ru/eng/mendc/v17/i1/p20
This publication is cited in the following 6 articles:
Jairton Dupont, Bárbara C. Leal, Pedro Lozano, Adriano L. Monteiro, Pedro Migowski, Jackson D. Scholten, “Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis”, Chem. Rev., 124:9 (2024), 5227
A. S. Kucherenko, D. E. Siyutkin, O. V. Maltsev, S. V. Kochetkov, S. G. Zlotin, “Asymmetric organocatalysis: from proline to highly efficient immobilized organocatalysts”, Russ Chem Bull, 61:7 (2012), 1313
V. Sargorovschi, N. Sucman, T. Iudin, D. Duca, E. Stingaci, D. Prodius, S. Pogrebnoi, F. Macaev, “Ionic Liquids Derivative of 1H-Imidazole as Novel Reagents, Catalysts and Solvents”, ChemJMold, 5:1 (2010), 36
S. G. Zlotin, N. N. Makhova, “Ionic liquids as substrate-specific recoverable solvents and catalysts of regio-, stereo- and enantioselective organic reactions”, Mendeleev Commun., 20:2 (2010), 63–71
Alexandre F. Trindade, Pedro M. P. Gois, Carlos A. M. Afonso, “Recyclable Stereoselective Catalysts”, Chem. Rev., 109:2 (2009), 418
Eugenia V. Starodubtseva, Olga V. Turova, Maxim G. Vinogradov, Lilia S. Gorshkova, Vladimir A. Ferapontov, Marina I. Struchkova, “A convenient route to chiral γ-lactones via asymmetric hydrogenation of γ-ketoesters using the RuCl3–BINAP–HCl catalytic system”, Tetrahedron, 64:51 (2008), 11713
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