Abstract:
Radical cations of trimethylene oxide under photobleaching at 77K could form either distonic radical cations ·CH2CH2CH=OH+/·CH2CH2O+=CH2 or oxetan-2-yl radicals depending on the Freon matrix used.
Document Type:
Article
Language: English
Citation:
M. Ya. Melnikov, V. N. Belevskii, A. D. Kalugina, O. L. Mel'nikova, V. I. Pergushov, D. A. Tyurin, “Photochemical reactions of trimethylene oxide radical cations in Freon matrices at 77K”, Mendeleev Commun., 18:6 (2008), 305–306
Linking options:
https://www.mathnet.ru/eng/mendc3336
https://www.mathnet.ru/eng/mendc/v18/i6/p305
This publication is cited in the following 4 articles:
M. Ya. Melnikov, O. I. Gromov, V. I. Pergushov, D. A. Pomogailo, I. D. Sorokin, “Photochemistry of Radical Cations of Some Organic Oxygen-Containing Compounds in Frozen Matrices”, Moscow Univ. Chem. Bull., 79:3 (2024), 147
Mikhail Ya. Melnikov, Oleg I. Gromov, Vladimir I. Pergushov, Daria A. Pomogailo, Ivan D. Sorokin, “PHOTOCHEMISTRY OF RADICAL CATIONS OF SOME ORGANIC OXYGEN-CONTAINING COMPOUNDS IN FROZEN MATRICES”, Lomonosov chemistry journal, 65:№3, 2024 (2024), 171
I. D. Sorokin, V. I. Pergushov, L. I. Savostina, M. Ya. Melnikov, “Phototransformations of azetidine radical cations stabilized in freonic matrices”, High Energy Chem, 48:3 (2014), 180
I. D. Sorokin, V. I. Feldman, O. L. Mel'nikova, V. I. Pergushov, D. A. Tyurin, M. Ya. Melnikov, “Reversible photochemical transformations of cis- and trans-2,3-dimethyloxirane radical cations in freonic matrices at 77K”, Mendeleev Commun., 21:3 (2011), 153–154
Contact us: