Abstract:
A series of phosphonium bis(ylide) rare-earth complexes of the type Cp*M(byl)2 (M=Sc, Y, Dy, Yb and Lu; byl=[Ph2P(CH2)2]−) has been synthesised and in three cases (Dy, Yb and Lu) structurally characterised revealing realization alongside with the chelating coordination mode for byl, also, for the first time, the bridging mode in dimeric Dy-complex.
Document Type:
Article
Language: English
Citation:
K. A. Rufanov, A. Spannenberg, “New rare-earth complexes with phosphonium bis(ylide) ligand [Ph2P(CH2)2]− and the first structural evidence for its bridging coordination mode”, Mendeleev Commun., 18:1 (2008), 32–34
Linking options:
https://www.mathnet.ru/eng/mendc3237
https://www.mathnet.ru/eng/mendc/v18/i1/p32
This publication is cited in the following 11 articles:
K. A. Rufanov, A. V. Shevelyukhina, “Synthesis of new π-stabilized organophosphorane bis-ylide ligands”, Russ Chem Bull, 72:6 (2023), 1438
R. Luisi, L. Degennaro, M. Colella, Comprehensive Organometallic Chemistry IV, 2022, 2
Taylor V. Fetrow, Rina Bhowmick, Andreas J. Achazi, Anastasia V. Blake, Francesca D. Eckstrom, Bess Vlaisavljevich, Scott R. Daly, “Chelating Borohydrides for Lanthanides and Actinides: Structures, Mechanochemistry, and Case Studies with Phosphinodiboranates”, Inorg. Chem., 59:1 (2020), 48
Konstantin A. Rufanov, Ilya Yu. Titov, Alex R. Petrov, Klaus Harms, Jörg Sundermeyer, “Synthesis of Binam‐P Derived C2‐Symmetric bis‐Iminophosphonamide Ligands. Molecular Structure of [(R)‐Binam(Ph2PN(H)tBu)2]”, Zeitschrift anorg allge chemie, 645:6-7 (2019), 559
Kevin R.D. Johnson, Breanne L. Kamenz, Paul G. Hayes, “Ligand influence on intramolecular cyclometalation in bis(phosphinimine) rare earth alkyl complexes”, Can. J. Chem., 94:4 (2016), 330
Konstantin A. Rufanov, Noa K. Pruß, Jörg Sundermeyer, “Simple entry into N-tert-butyl-iminophosphonamide rare-earth metal alkyl and chlorido complexes”, Dalton Trans., 45:4 (2016), 1525
Fernando López Ortiz, Lithium Compounds in Organic Synthesis, 2014, 271
Irina L. Odinets, Organophosphorus Chemistry, 2010, 94
John G. Brennan, Andrea Sella, Organometallic Chemistry, 2010, 121
Alex R. Petrov, Michael Elfferding, Juri Möbus, Klaus Harms, Konstantin A. Rufanov, Jörg Sundermeyer, “Discovery and Synthetic Value of a Novel, Highly Crowded Cyclopentadienylphosphane Ph2P‐CpTMH and Its Ferrocenyl‐Bisphosphane dppfTM”, Eur J Inorg Chem, 2010:26 (2010), 4157
A. R. Petrov, K. A. Rufanov, N. K. Hangaly, M. Elfferding, K. Harms, J. Sundermeyer, “Air-stable helical bis(cyclopentadienylphosphazene) complexes of divalent ytterbium”, Mendeleev Commun., 20:4 (2010), 197–199
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