Abstract:
The presence of the =C–H···:C intermolecular hydrogen bond in 1,3-di-tert-butylimidazol-2-ylidene has been demonstrated by vibrational spectroscopy and confirmed by X-ray diffraction analysis and quantum-chemical calculations.
Document Type:
Article
Language: English
Citation:
L. A. Leites, G. I. Magdanurov, S. S. Bukalov, R. West, “Intermolecular =C–H···:C hydrogen bond in a crystalline unsaturated Arduengo-type carbene”, Mendeleev Commun., 18:1 (2008), 14–15
Linking options:
https://www.mathnet.ru/eng/mendc3230
https://www.mathnet.ru/eng/mendc/v18/i1/p14
This publication is cited in the following 15 articles:
Mathias Paul, Thomas Thomulka, Wacharee Harnying, Jörg-Martin Neudörfl, Charlie R. Adams, Jonathan Martens, Giel Berden, Jos Oomens, Anthony J. H. M. Meijer, Albrecht Berkessel, Mathias Schäfer, “Hydrogen Bonding Shuts Down Tunneling in Hydroxycarbenes: A Gas-Phase Study by Tandem-Mass Spectrometry, Infrared Ion Spectroscopy, and Theory”, J. Am. Chem. Soc., 145:22 (2023), 12124
Martin Wild, Ferdinand Stolz, Sergej Naumov, Bernd Abel, “On the in situ formation of carbenes in ionic liquids”, Molecular Physics, 119:17-18 (2021)
Oldamur Hollóczki, “The Mechanism of N‐Heterocyclic Carbene Organocatalysis through a Magnifying Glass”, Chemistry A European J, 26:22 (2020), 4885
Zacharias J. Kinney, Arnold L. Rheingold, John D. Protasiewicz, “Preferential N–H⋯:C hydrogen bonding involving ditopic NH-containing systems and N-heterocyclic carbenes”, RSC Adv., 10:69 (2020), 42164
Yi Wang, Zhi-Xiang Yu, “Symmetric C···H···C Hydrogen Bonds Predicted by Quantum Chemical Calculations”, J. Org. Chem., 85:2 (2020), 397
Mathias Paul, Eric Detmar, Maria Schlangen, Martin Breugst, Jörg‐Martin Neudörfl, Helmut Schwarz, Albrecht Berkessel, Mathias Schäfer, “Intermediates of N‐Heterocyclic Carbene (NHC) Dimerization Probed in the Gas Phase by Ion Mobility Mass Spectrometry: C-H⋅⋅⋅:C Hydrogen Bonding Versus Covalent Dimer Formation”, Chemistry A European J, 25:10 (2019), 2511
Sascha Gehrke, Oldamur Hollóczki, “Hydrogen Bonding of N‐Heterocyclic Carbenes in Solution: Mechanisms of Solvent Reorganization”, Chemistry A European J, 24:45 (2018), 11594
Roman Michez, Thomas Doneux, Claudine Buess‐Herman, Michel Luhmer, “NMR Study of the Reductive Decomposition of [BMIm][NTf2] at Gold Electrodes and Indirect Electrochemical Conversion of CO2”, ChemPhysChem, 18:16 (2017), 2208
David Specklin, Christophe Fliedel, Christophe Gourlaouen, Jean‐Charles Bruyere, Teresa Avilés, Corinne Boudon, Laurent Ruhlmann, Samuel Dagorne, “N‐Heterocyclic Carbene Based Tri‐organyl‐Zn–Alkyl Cations: Synthesis, Structures, and Use in CO2 Functionalization”, Chemistry A European J, 23:23 (2017), 5509
Sascha Gehrke, Oldamur Hollóczki, “A molecular mechanical model for N-heterocyclic carbenes”, Phys. Chem. Chem. Phys., 18:32 (2016), 22070
Oldamur Hollóczki, “Unveiling the peculiar hydrogen bonding behavior of solvated N-heterocyclic carbenes”, Phys. Chem. Chem. Phys., 18:1 (2016), 126
Thorge Brünig, Kristijan Krekić, Clemens Bruhn, Rudolf Pietschnig, “Calorimetric Studies and Structural Aspects of Ionic Liquids in Designing Sorption Materials for Thermal Energy Storage”, Chemistry A European J, 22:45 (2016), 16200
Chengfu Pi, Xiaoling Yu, Wenjun Zheng, “Imidazolium 1,3‐Benzazaphospholide Ion Pairs with Strong C–H···N Hydrogen Bonds – Synthesis, Structures, and Reactivity”, Eur J Inorg Chem, 2015:10 (2015), 1804
Martin Thomas, Martin Brehm, Oldamur Hollóczki, Barbara Kirchner, “How Can a Carbene be Active in an Ionic Liquid?”, Chemistry A European J, 20:6 (2014), 1622
Oldamur Hollóczki, László Nyulászi, Topics in Current Chemistry, 351, Electronic Effects in Organic Chemistry, 2013, 1