Abstract:
Within the series of model N-diorganophosphoryl-N′-n-octylureas, the ability to extract uranium(VI) from nitric acid solutions is maximal for N-diphenylphosphoryl derivative and sharply decreases when phenyl groups are replaced with n-alkyl or cycloalkyl substituents; this indicates the presence of ‘anomalous aryl strengthening’ effect also in the series of N-phosphorylureas, a new promising class of organophosphorus extractants.
Document Type:
Article
Language: English
Citation:
A. M. Safiulina, E. I. Goryunov, A. A. Letyushov, I. B. Goryunova, S. A. Smirnova, A. G. Ginzburg, I. G. Tananaev, E. E. Nifantyev, B. F. Myasoedov, “Effect of anomalous aryl strengthening in the series of N-phosphorylureas”, Mendeleev Commun., 19:5 (2009), 263–265
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