Abstract:
The Schmidt reaction of aryl methyl ketones in ionic liquids (optimally in 1-ethyl-3-methylimidazolium triflate with CF3SO3H additive) proceeds at 40°C within 10–30 h to give the corresponding acetanilides in good yields.
Document Type:
Article
Language: English
Citation:
M. A. Epishina, A. S. Kulikov, N. V. Ignat'ev, M. Schulte, N. N. Makhova, “The first example of the Schmidt reaction in ionic liquids”, Mendeleev Commun., 20:6 (2010), 335–336
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https://www.mathnet.ru/eng/mendc3084
https://www.mathnet.ru/eng/mendc/v20/i6/p335
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Galina V. Kryshtal, Galina M. Zhdankina, Nikolai V. Ignat'ev, Michael Schulte, Sergei G. Zlotin, “The orthoester Johnson–Claisen rearrangement of allylic terpenols in the presence of acidic ionic liquid”, Journal of Fluorine Chemistry, 183 (2016), 23
J. Aubé, C. Fehl, R. Liu, M.C. McLeod, H.F. Motiwala, Comprehensive Organic Synthesis II, 2014, 598
N. N. Makhova, M. I. Pleshchev, M. A. Epishina, A. S. Kulikov, “Synthesis and Transformations of Nitrogen Heterocycles in Ionic Liquids (Review)”, Chem Heterocycl Comp, 50:5 (2014), 634
Nam T. S. Phan, Ky K. A. Le, Thien V. Nguyen, Nhan T. H. Le, “Chitosan as a Renewable Heterogeneous Catalyst for the Knoevenagel Reaction in Ionic Liquid as Green Solvent”, ISRN Organic Chemistry, 2012 (2012), 1
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M. A. Epishina, A. S. Kulikov, M. I. Struchkova, N. V. Ignat'ev, M. Schulte, N. N. Makhova, “Ionic Liquids-assisted Synthesis of 3,4-Dihydroisoquinolines by the Bishler–Napieralski Reaction”, Mendeleev Commun., 22:5 (2012), 267–269
Margarita A. Epishina, Alexander S. Kulikov, Nikolai V. Ignat'ev, Michael Schulte, Nina N. Makhova, “ChemInform Abstract: The First Example of the Schmidt Reaction in Ionic Liquids.”, ChemInform, 42:11 (2011)
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