This article is cited in 12 scientific papers (total in 12 papers)
Synthesis of new spirophosphoranes bearing the phosphorus–carbon bond by cascade reactions of 2-(2-methyl-4-oxopent-2-yloxy)benzo- 1,3,2-dioxaphosphole with activated carbonyl compounds
Abstract:
Cascade reactions of 2-(2-methyl-4-oxopent-2-yloxy)benzo-σ3λ3-1,3,2-dioxaphosphole with chloral, hexafluoroacetone, mezoxalic acid diethyl ester and trifluoropyruvic acid ethyl ester are a versatile approach to the synthesis of spirophosphoranes bearing a phosphorus–carbon bond with a high yield and stereoselectivity.
Document Type:
Article
Language: English
Citation:
L. M. Abdrakhmanova, V. F. Mironov, M. N. Dimukhametov, D. B. Krivolapov, I. A. Litvinov, “Synthesis of new spirophosphoranes bearing the phosphorus–carbon bond by cascade reactions of 2-(2-methyl-4-oxopent-2-yloxy)benzo- 1,3,2-dioxaphosphole with activated carbonyl compounds”, Mendeleev Commun., 20:1 (2010), 41–43
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This publication is cited in the following 12 articles:
Jozef Drabowicz, Rafal Karpowicz, Dorota Krasowska, Luca Sancineto, Christian V. Stevens, Comprehensive Heterocyclic Chemistry IV, 2022, 633
R. Pajkert, G.-V. Röschenthaler, Knowledge Updates 2022/1, 2022
V. F. Mironov, M. N. Dimukhametov, Ya. S. Blinova, F. Kh. Karataeva, “Simultaneous Formation of Cage and Spirane Pentaalkoxyphosphoranes in Reaction of 5,5-Dimethyl-2-(2-oxo-1,2-diphenylethoxy)-1,3,2-dioxaphosphorinane with Hexafluoroacetone”, Russ J Gen Chem, 90:11 (2020), 2080
V. F. Mironov, T. A. Baronova, M. N. Dimukhametov, R. R. Fayzullin, I. A. Litvinov, “The reaction of 4-(1,3,2-benzodioxaphosphol-2-yloxy)-3-tert-butylpent-4-en-2-one with hexafluoroacetone”, Mendeleev Commun., 29:5 (2019), 506–508
Nadezhda R. Khasiyatullina, Tamara A. Baronova, Ekaterina V. Mironova, Robert R. Fayzullin, Igor A. Litvinov, Sergey V. Efimov, Rashid Z. Musin, Vladimir V. Klochkov, Vladimir F. Mironov, “Tandem dihetero-Diels–Alder and Huisgen cycloaddition reactions. Synthesis, crystal structure and hydrolysis of the novel cage phosphoranes”, Org. Chem. Front., 5:21 (2018), 3113
N. R. Khasiyatullina, V. F. Mironov, E. V. Mironova, D. B. Krivolapov, I. A. Litvinov, “Preparation and crystal structure of 1,1-tetramethylethylenedioxy-3,4-diphenyl-6-trichloromethyl-2,5,7,1-trioxaphosphabicyclo[2.2.11,4]heptane and 2-(1-hydroxy-2,2,2-trichloroethoxy)-4,4,5,5-tetramethyl- 2-oxo-1,3,2-dioxaphospholane”, Russ J Gen Chem, 86:3 (2016), 551
Vladimir F. Mironov, Mudaris N. Dimukhametov, Sergey V. Efimov, Roza M. Aminova, Farida Kh. Karataeva, Dmitry B. Krivolapov, Ekaterina V. Mironova, Vladimir V. Klochkov, “Stereoselective PCO/POC-Rearrangement of P–C-Cage Phosphorane in the Reaction of 4,5-Dimethyl-2-(2-oxo-1,2-diphenyl)ethoxy-1,3,2-dioxaphospholane with Hexafluoroacetone”, J. Org. Chem., 81:14 (2016), 5837
V. F. Mironov, T. A. Baronova, E. V. Mironova, M. N. Dimukhametov, D. B. Krivolapov, L. M. Abdrakhmanova, “Synthesis and steric structure of 3′,3′,5′-trimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]octane] and 3′,5′-dimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]oct[3]ene]”, Russ J Org Chem, 51:3 (2015), 401
V. F. Mironov, M. N. Dimukhametov, E. V. Mironova, D. B. Krivolapov, L. M. Abdrakhmanova, “Caged C-P phosphoranes based on 2-(2-methyl-4-oxopent-2-yloxy)- and 2-[2-(methylcarbonyl)-1-phenoxy]-1,3,2-benzodioxaphospholes and diethyl mesoxalate”, Russ J Gen Chem, 85:2 (2015), 441
Liliya Abdrakhmanova, Arturo Espinosa, Rainer Streubel, “Reaction of Li/Cl phosphinidenoid complexes with a phosphite substituted ketone: access to complexes with a novel mixed-valence polycyclic P,C-ligand system”, Dalton Trans., 42:29 (2013), 10510
Romana Pajkert, Gerd-Volker Röschenthaler, Organophosphorus Chemistry, 2012, 322
Liliya M. Abdrakhmanova, Vladimir F. Mironov, Mudaris N. Dimukhametov, Dmitry B. Krivolapov, Igor A. Litvinov, “ChemInform Abstract: Synthesis of New Spirophosphoranes Bearing the Phosphorus—Carbon Bond by Cascade Reactions of 2‐(2‐Methyl‐4‐oxopent‐2‐yloxy)benzo‐1,3,2‐dioxaphosphole with Activated Carbonyl Compounds.”, ChemInform, 41:25 (2010)