Abstract:
The reaction of DyI2 with substituted 2-pyridyl amide [N(SiMe3)(2-C5H3N-6-Me)]– (L) and lithium alkoxide can give a new complex [{(L)2Dy(μ2-OBut)Li}2(μ4-O)] with a Dy2Li2O group, which was characterized by X-ray crystallography.
Citation:
Ch.-L. Pan, Sh.-D. Sheng, J. Wang, Yu.-S. Pan, “Cleavage and capture of tetrahydrofuran by dysprosium(II) species: a novel tetranuclear Dy2Li2O unit”, Mendeleev Commun., 21:6 (2011), 318–319
Linking options:
https://www.mathnet.ru/eng/mendc2957
https://www.mathnet.ru/eng/mendc/v21/i6/p318
This publication is cited in the following 9 articles:
Daniel Werner, Zhifang Guo, Glen B. Deacon, Peter C. Junk, “Synthesis and Structures of Oxide ‐Centred Alkali Metal (K, Li)/Lanthanoid (Ln3 or 4) 3,5‐Dimethylpyrazolate Cages ‐ Herbert Schumann Revisited”, Chemistry — An Asian Journal, 2024
Ionel Haiduc, Comprehensive Coordination Chemistry III, 2021, 66
Nicole Harmgarth, Phil Liebing, Liane Hilfert, Volker Lorenz, Felix Engelhardt, Sabine Busse, Frank T. Edelmann, “New Homoleptic Rare‐Earth Metal Complexes Comprising the Unsymmetrically Substituted Amidinate Ligand [MeC(NEt)(NtBu)]–”, Zeitschrift anorg allge chemie, 645:17 (2019), 1101
Ionel Haiduc, “Inverse coordination – An emerging new chemical concept. Oxygen and other chalcogens as coordination centers”, Coordination Chemistry Reviews, 338 (2017), 1
Michal Szostak, Malcolm Spain, David J. Procter, “Uncovering the Importance of Proton Donors in TmI2‐Promoted Electron Transfer: Facile CN Bond Cleavage in Unactivated Amides”, Angew Chem Int Ed, 52:28 (2013), 7237
Fabrizio Ortu, Graeme J. Moxey, Alexander J. Blake, William Lewis, Deborah L. Kays, “Alkaline Earth Complexes of Silylated Aminopyridinato Ligands: Homoleptic Compounds and Heterobimetallic Coordination Polymers”, Inorg. Chem., 52:21 (2013), 12429
Frank T. Edelmann, Advances in Organometallic Chemistry, 61, 2013, 55
Michal Szostak, Malcolm Spain, David J. Procter, “Uncovering the Importance of Proton Donors in TmI2‐Promoted Electron Transfer: Facile CN Bond Cleavage in Unactivated Amides”, Angewandte Chemie, 125:28 (2013), 7378
Frank T. Edelmann, “Lanthanide amidinates and guanidinates in catalysis and materials science: a continuing success story”, Chem. Soc. Rev., 41:23 (2012), 7657
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