Abstract:
Reduction of the title ozonide with 1 equiv. of sodium borohydride in ethanol leads to the transformation of the ozonide moiety into d-lactone one, whereas the use of 5 equiv. of the reductant affords the corresponding 1,5-diol, with N-deacylation occurring in all cases.
Keywords:
δ-Lactones, ozonides, reduction.
Document Type:
Article
Language: English
Citation:
A. G. Tolstikov, R. G. Savchenko, S. R. Afonkina, E. S. Lukina, D. V. Nedopekin, L. M. Khalilov, V. N. Odinokov, “Sodium borohydride reduction of 4-aryl-N-trifluoroacetyl-3a,4,5,9b-tetrahydro-3H-cyclopenta[c]quinoline ozonide”, Mendeleev Commun., 21:5 (2011), 285–286
Linking options:
https://www.mathnet.ru/eng/mendc2946
https://www.mathnet.ru/eng/mendc/v21/i5/p285
This publication is cited in the following 1 articles:
Alexander G. Tolstikov, Rimma G. Savchenko, Svetlana R. Afon'kina, Elena S. Lukina, Denis V. Nedopekin, Leonard M. Khalilov, Victor N. Odinokov, “ChemInform Abstract: Sodium Borohydride Reduction of 4‐Aryl‐N‐trifluoroacetyl‐3a,4,5,9b‐tetrahydro‐3H‐cyclopenta[c]quinoline Ozonide.”, ChemInform, 43:10 (2012)