Abstract:
The X-ray irradiation of 2,2-dimethyloxirane in freonic matrices at 77K results in the trapping of a cyclic radical cation form, presumably, complexed with a matrix molecule, which transforms into a C-centered distonic radical cation under the action of light.
Document Type:
Article
Language: English
Citation:
I. D. Sorokin, V. I. Feldman, O. L. Mel'nikova, V. I. Pergushov, D. A. Tyurin, M. Ya. Melnikov, “The nature and photochemistry of 2,2-dimethyloxirane radical cations in freonic matrices at 77K”, Mendeleev Commun., 21:3 (2011), 155–156
Linking options:
https://www.mathnet.ru/eng/mendc2900
https://www.mathnet.ru/eng/mendc/v21/i3/p155
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