Abstract:
1-Methyl-3,4,5-trinitropyrazole in reaction with thiols, phenols, oximes, ammonia, amines and NH-azoles gives substitution products of the 5-positioned nitro group.
Citation:
I. L. Dalinger, I. A. Vatsadze, T. K. Shkineva, G. P. Popova, S. A. Shevelev, “Nucleophilic substitution in 1-methyl-3,4,5-trinitro-1H-pyrazole”, Mendeleev Commun., 21:3 (2011), 149–150
Linking options:
https://www.mathnet.ru/eng/mendc2897
https://www.mathnet.ru/eng/mendc/v21/i3/p149
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Mikhail E. Kletskii, Oleg N. Burov, Igor L. Dalinger, Svyatoslav A. Shevelev, “The mechanisms of nucleophilic substitution in 1-methyl-3,4,5-trinitropyrazole”, Computational and Theoretical Chemistry, 1033 (2014), 31
Thomas M. Klapötke, Alexander Penger, Carolin Pflüger, Jörg Stierstorfer, Muhamed Sućeska, “Advanced Open‐Chain Nitramines as Energetic Materials: Heterocyclic‐Substituted 1,3‐Dichloro‐2‐nitrazapropane”, Eur J Inorg Chem, 2013:26 (2013), 4667
I. L. Dalinger, D. V. Khakimov, T. K. Shkineva, I. A. Vatsadze, G. P. Popova, T. S. Pivina, S. A. Shevelev, “Quantum-chemical study of the reactivity of di- and trinitropyrazoles”, Chem Heterocycl Comp, 48:11 (2013), 1646
I. A. Vatsadze, I. L. Dalinger, T. K. Shkineva, G. P. Popova, S. A. Shevelev, “Nitropyrazoles 22. On reactivity of 3,5-dinitro-4-(phenylsulfonyl)pyrazole and its N-methyl derivative”, Russ Chem Bull, 61:2 (2012), 469
I. L. Dalinger, I. A. Vatsadze, T. K. Shkineva, G. P. Popova, S. A. Shevelev, “Nitropyrazoles 20. Synthesis and transformations of 1-methoxymethyl-3,4,5-trinitropyrazole”, Russ Chem Bull, 61:2 (2012), 464
I. L. Dalinger, I. A. Vatsadze, T. K. Shkineva, G. P. Popova, S. A. Shevelev, “Hydrogen halides as nucleophilic agents for 3,4,5-trinitro-1H-pyrazoles”, Mendeleev Commun., 22:1 (2012), 43–44
Igor L. Dalinger, Irina A. Vatsadze, Tatyana K. Shkineva, Galina P. Popova, Svyatoslav A. Shevelev, “ChemInform Abstract: Nucleophilic Substitution in 1‐Methyl‐3,4,5‐trinitro‐1H‐pyrazole”, ChemInform, 42:42 (2011)
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