Abstract:
A new method for the synthesis of volatile tin(ii) hexafluoroacetylacetonate [Sn(C5HO2F6)2] was suggested, the compound was characterized by elemental analysis, IR spectroscopy, and DTA/TGA; the crystal structure was established by X-ray diffraction; the morphology and composition of the coating deposited by atmospheric pressure chemical vapour deposition were studied by SEM-EDX and XRD.
Keywords:
CVD, tin oxide, films, precursor, tin hexafluoroacetylacetonate.
Document Type:
Article
Language: English
Citation:
V. G. Sevastyanov, E. P. Simonenko, P. A. Ignatov, V. S. Popov, A. V. Churakov, N. T. Kuznetsov, V. S. Sergienko, “Tin(ii) Hexafluoroacetylacetonate as a Precursor in Atmospheric Pressure Chemical Vapour Deposition: Synthesis, Structure and Properties”, Mendeleev Commun., 22:5 (2012), 239–241
Linking options:
https://www.mathnet.ru/eng/mendc2804
https://www.mathnet.ru/eng/mendc/v22/i5/p239
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Jessica K. Elinburg, Ariel S. Hyre, James McNeely, Todd M. Alam, Steffen Klenner, Rainer Pöttgen, Arnold L. Rheingold, Linda H. Doerrer, “Formation of monomeric Sn(ii) and Sn(iv) perfluoropinacolate complexes and their characterization by 119Sn Mössbauer and 119Sn NMR spectroscopies”, Dalton Trans., 49:39 (2020), 13773
V. S. Popov, P. A. Ignatov, A. V. Churakov, E. P. Simonenko, N. P. Simonenko, N. N. Ignatova, V. G. Sevast'yanov, N. T. Kuznetsov, “Tin trifluoroacetylacetonate [Sn(C5H4O2F3)2] as a precursor of tin dioxide in APCVD process”, Russ. J. Inorg. Chem., 61:5 (2016), 545
Tomáš Chlupatý, Zdeňka Růžičková, Michal Horáček, Mercedes Alonso, Frank De Proft, Hana Kampová, Jiří Brus, Aleš Růžička, “Oxidative Additions of Homoleptic Tin(II) Amidinate”, Organometallics, 34:3 (2015), 606
Tomáš Chlupatý, Zdeňka Růžičková, Michal Horáček, Jan Merna, Mercedes Alonso, Frank De Proft, Aleš Růžička, “Reactivity of Tin(II) Guanidinate with 1,2- and 1,3-Diones: Oxidative Cycloaddition or Ligand Substitution ?”, Organometallics, 34:11 (2015), 2202
T. Křenek, P. Duchek, M. Urbanová, D. Pokorná, P. Bezdička, I. Jakubec, M. Pola, R. Čerstvý, T. Kovářík, A. Galiková, J. Pola, “Thermal co-decomposition of silver acetylacetonate and tin(II) hexafluoroacetylacetonate: Formation of carbonaceous Ag/AgxSn(x=4 and 6.7)/SnO2 composites”, Thermochimica Acta, 566 (2013), 92
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