Abstract:
The first example of nitric oxide fixation by nontransition metal complexes was found: lead(ii) and zinc(ii) catecholato complexes readily react with nitric oxide to give the corresponding nitrosyl-containing mono-o-semiquinonates; the process of binding and transfer of NO can be easily monitored by EPR spectroscopy.
Keywords:
redox-active ligands, catecholate, lead(II), zinc(II), NO binding, EPR.
Citation:
E. V. Ilyakina, A. I. Poddel'sky, V. K. Cherkasov, G. A. Abakumov, “Binding of NO by Nontransition Metal Complexes”, Mendeleev Commun., 22:4 (2012), 208–210
Linking options:
https://www.mathnet.ru/eng/mendc2793
https://www.mathnet.ru/eng/mendc/v22/i4/p208
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