Abstract:
The electrochemical reduction of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione in DMSO, MeCN and HMPA is an EE process, which is characterized by two separate one electron reversible peaks on cyclic voltammograms, first peak retains reversibility in DMSO–H2O mixtures, corresponding radical anions were obtained by one electron reduction of the above compounds and characterized by EPR and DFT calculations at the (U)B3LYP/6-31+G* level of theory.
Citation:
N. V. Vasilieva, I. G. Irtegova, V. A. Loskutov, L. A. Shundrin, “Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione”, Mendeleev Commun., 22:2 (2012), 111–113
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https://www.mathnet.ru/eng/mendc2758
https://www.mathnet.ru/eng/mendc/v22/i2/p111
This publication is cited in the following 4 articles:
I. K. Shundrina, I. A. Os'kina, D. S. Odintsov, A. A. Gismatulin, I. A. Azarov, L. A. Shundrin, V. A. Gritsenko, “Octafluorobiphenyl-4,4'-diyl 9-oxothioxanthene-1,4-diyl polyether – a promising material for organic film based memristors: synthesis, memristive effect and charge transport mechanism”, Mendeleev Commun., 34:5 (2024), 667–669
Danila S. Odintsov, Irina A. Os'kina, Irina G. Irtegova, Leonid A. Shundrin, “Electrochemical Reduction of 1H‐Thioxanthene‐1,4,9‐trione and 3‐Methyl‐1H‐thioxanthene‐1,4,9‐trione – Representatives of a New Class of Heterocycles Related to Thioxanthenone”, Eur J Org Chem, 26:33 (2023)
Nuno R. Candeias, Alexander Efimov, Comprehensive Heterocyclic Chemistry IV, 2022, 512
N. V. Vasilieva, I. G. Irtegova, V. A. Loskutov, L. A. Shundrin, “Redox properties and radical anions of 2-substituted thioxanthen-9-ones and their 2-methyl S-oxide derivatives”, Mendeleev Commun., 23:6 (2013), 334–336
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