Abstract:
A new method for the synthesis of calcium and magnesium fluorides with high surface areas is proposed; the fluorides obtained by the decomposition of β-cyclodextrin–metal trifluoroacetate mixtures have surface areas of about 80 and 60 m2 g−1 for CaF2 and MgF2, respectively.
Citation:
S. Yu. Arkhipenko, A. A. Fedorova, I. V. Morozov, A. S. Shaporev, “Preparation of calcium and magnesium fluorides with extended surface areas using β-cyclodextrin as a structure-forming agent”, Mendeleev Commun., 22:1 (2012), 25–26
Linking options:
https://www.mathnet.ru/eng/mendc2725
https://www.mathnet.ru/eng/mendc/v22/i1/p25
This publication is cited in the following 6 articles:
Yawen Wang, Zahra Gohari Bajestani, Jérôme Lhoste, Sandy Auguste, Annie Hémon-Ribaud, Monique Body, Christophe Legein, Vincent Maisonneuve, Amandine Guiet, Sylvette Brunet, “The Effects of Various Parameters of the Microwave-Assisted Solvothermal Synthesis on the Specific Surface Area and Catalytic Performance of MgF2 Nanoparticles”, Materials, 13:16 (2020), 3566
V. G. Ilves, S. Yu. Sokovnin, M. G. Zuev, M. A. Uimin, M. Rähn, J. Kozlova, V. Sammelselg, “Effect of annealing on structural, textural, thermal, magnetic, and luminescence properties of calcium fluoride nanoparticles”, Phys. Solid State, 61:11 (2019), 2200–2217
A. Astruc, S. Célérier, E. Pavon, A.-S. Mamede, L. Delevoye, S. Brunet, “Mixed Ba1-xLaxF2+x fluoride materials as catalyst for the gas phase fluorination of 2-chloropyridine by HF”, Applied Catalysis B: Environmental, 204 (2017), 107
Anna A. Fedorova, Andrey I. Fedulin, Igor V. Morozov, “New method of beta-NaYF4: Yb3+, Er3+ synthesis by using beta-cyclodextrin”, Journal of Fluorine Chemistry, 178 (2015), 173
A.A. Fedorova, S.Yu. Arkhipenko, E.R. Fatula, N.P. Chikov, N.M. Sorokina, I.V. Morozov, “The Novel Method of Synthesis of Solid Solutions LnxCa1-xF2+x (Ln=Yb, Nd) Using Beta-cyclodextrin”, Procedia Chemistry, 11 (2014), 20
Arnaud Astruc, Cindy Cochon, Samuel Dessources, Stéphane Célérier, Sylvette Brunet, “High specific surface area metal fluorides as catalysts for the fluorination of 2-chloropyridine by HF”, Applied Catalysis A: General, 453 (2013), 20