Abstract:
The μ-diborolyl triple-decker complex CpCo(μ-1,3-C3B2Me5)PtMe3 was prepared by reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]–with [PtMe3I]4; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C3B2Me5)]– and [PtMe3]+ fragments are ∼64% electrostatic and 36% covalent.
Citation:
A. S. Romanov, D. V. Muratov, P. V. Petrovskii, W. Siebert, A. R. Kudinov, “The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3”, Mendeleev Commun., 22:1 (2012), 13–14
Linking options:
https://www.mathnet.ru/eng/mendc2720
https://www.mathnet.ru/eng/mendc/v22/i1/p13
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