Abstract:
Ring opening in 6-aryl-1,5-diazabicyclo[3.1.0]hexanes gives cyclic azomethine imines which are prone to exchange of arylidene moiety with (het)arylidenemalononitriles to form the metathesis products being new azomethine imines. These species were fixed as pyrazolines due to the 1,4-H shift or trapped by dimethyl acetylenedicarboxylate or CS2.
Citation:
M. I. Pleshchev, V. Yu. Petukhova, V. V. Kuznetsov, D. V. Khakimov, T. S. Pivina, M. I. Struchkova, Yu. V. Nelyubina, N. N. Makhova, “Metathesis of Azomethine Imines in Reaction of 6-aryl-1,5-Diazabicyclo[3.1.0]Hexanes with (Het)Arylidenemalononitriles”, Mendeleev Commun., 23:1 (2013), 34–36
Linking options:
https://www.mathnet.ru/eng/mendc2604
https://www.mathnet.ru/eng/mendc/v23/i1/p34
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